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共轭聚合物光催化合成过氧化氢改性策略的研究进展

张琦 汪锋

武汉工程大学学报2025,Vol.47Issue(2):135-142,8.
武汉工程大学学报2025,Vol.47Issue(2):135-142,8.DOI:10.19843/j.cnki.CN42-1779/TQ.202411011

共轭聚合物光催化合成过氧化氢改性策略的研究进展

Research progress on modification strategies of conjugated polymers for photocatalytic production of hydrogen peroxide

张琦 1汪锋1

作者信息

  • 1. 武汉工程大学化工与制药学院,新型反应器与绿色化学工艺湖北省重点实验室,湖北 武汉 430205
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摘要

Abstract

Traditional synthesis methods of hydrogen peroxide(H2O2)have problems such as high energy consumption and safety hazards.Photocatalytic synthesis of H2O2 has the advantages of being safe,environment-friendly and energy efficient,meeting the requirements of sustainable development,and showing great development potential.As typical photocatalytic materials,conjugated polymers have become an approach to solving these problems by enhancing their photocatalytic properties through structural modification.Based on the mechanism of photocatalytic synthesis of H2O2,this review summarizes the research progress in modification strategies of conjugated polymers in the field of photocatalysis,focusing on the effects of surface modification,donor-acceptor structure construction,heterojunction system construction,and catalytic site regulation on the performance of photocatalytic synthesis of H2O2.Given that conjugated polymers are prone to electron-hole pair recombination,optimizing H2O2 generation pathway and developing gas-liquid-solid three-phase photocatalytic system are proposed as the main research directions for photocatalytic H2O2 generation with conjugated polymers in the future,providing new ideas for designing efficient,green and stable photocatalysts.

关键词

光催化/共轭聚合物/过氧化氢/改性/研究进展

Key words

photocatalysis/conjugated polymer/hydrogen peroxide/modification/research progress

分类

化学

引用本文复制引用

张琦,汪锋..共轭聚合物光催化合成过氧化氢改性策略的研究进展[J].武汉工程大学学报,2025,47(2):135-142,8.

基金项目

湖北省教育厅重点项目(D20181505) (D20181505)

光电化学材料与器件教育部重点实验室开放基金(JDGD-202003) (JDGD-202003)

武汉工程大学学报

1674-2869

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