化工进展2025，Vol.44Issue(4)：2172-2182,11.DOI:10.16085/j.issn.1000-6613.2024-0627
电解法制备次氯酸钠用电极材料的研究进展
Research progress on electrode materials for the preparation of sodium hypochlorite by electrolysis
摘要
Abstract
Sodium hypochlorite(NaClO)is widely used as an efficient and inexpensive disinfectant.Electrolysis is a convenient and effective way to produce NaClO with electrodes being the core component of a NaClO generator.These electrodes determine the device's chlorine evolution efficiency,energy consumption and service life.Currently,titanium electrodes coated with mixed metal oxides(Ti/MMO)have become a research focus due to their excellent electrocatalytic activity,long service life and low energy consumption.However,the production cost remains high due to the use of precious metal materials.This paper summarized various electrode materials used for the electrolytic production of NaClO,their composition,performance and development trends.It analyzed the reasons for the passivation of early dimensionally stable anodes(DSA)and focused on three approaches for optimizing electrode preparation processes.Considering current research challenges,the paper anticipated the future development directions of electrode materials,highlighting the rational selection and diversification of metal elements in coatings,the introduction of titanium dioxide nanotube arrays(TNT)intermediate layers via in-situ anodic oxidation,and the combination of hydrothermal synthesis method for electrode preparation as key aspects of process optimization.关键词
次氯酸钠/电解法/电极/析氯性能/制备工艺Key words
sodium hypochlorite/electrolysis/electrode/chlorine evolution performance/preparation technology分类
化学工程引用本文复制引用
王浩,李新杰..电解法制备次氯酸钠用电极材料的研究进展[J].化工进展,2025,44(4):2172-2182,11.基金项目
南京理工大学校企合作技术开发项目(20210701). （20210701）
