化工学报2025，Vol.76Issue(4)：1391-1403,13.DOI:10.11949/0438-1157.20241161
液-液非均相反应与传递过程强化方法研究进展
Research progress of liquid-liquid heterogeneous reactions and intensification methods towards their transfer processes
摘要
Abstract
Liquid-liquid heterogeneous reactions are widely involved in various fields of the petrochemical and fine chemical industries.Owing to the difference in the physical and chemical properties of the liquid-liquid phase and the existence of the phase interface,the liquid-liquid heterogeneous reaction process is usually affected by both intrinsic reaction kinetics and the transfer process.Therefore,enhancing the liquid-liquid heterogeneous reaction transfer process and matching it with the reaction kinetics to achieve efficient utilization of raw materials and energy has always been one of the hot topics of researchers.Focusing on the intensifying mechanism and application of the liquid-liquid heterogeneous reactions and transfer processes,this paper takes typical heterogeneous reactions such as nitrification and dehydrochlorination reactions as examples,combined with the basic characteristics of reaction kinetics,thermodynamics and transfer processes,reviews the mechanism of the effect of the transfer-reaction process coupling on reaction selectivity and spatio-temporal yield,and describes the challenges faced by industrial applications and the solutions by process intensification.Furthermore,the application potential of liquid-liquid heterogeneous reaction process intensification is prospected from the perspective of matching the reaction and transfer processes.关键词
液-液非均相反应/本征动力学/质量传递/热量传递/过程强化Key words
liquid-liquid heterogeneous reaction/intrinsic dynamics/mass transfer/heat transfer/process intensification分类
化学化工引用本文复制引用
马韶阳,徐涵卓,张亮亮,孙宝昌,邹海魁,罗勇,初广文..液-液非均相反应与传递过程强化方法研究进展[J].化工学报,2025,76(4):1391-1403,13.基金项目
国家自然科学基金项目(22288102) （22288102）
