天津工业大学学报2025，Vol.44Issue(2)：43-50,8.DOI:10.3969/j.issn.1671-024x.2025.02.007
碳载硫化铑催化剂在酸性体系中的氢氧化性能
Hydrogen oxidation performance of carbon-supported rhodium sulfide catalyst in acidic system
摘要
Abstract
To address the issue of poor stability of traditional commercial Pt/C electrocatalysts in acidic electrolytes,espe-cially in hydrochloric acid,a stable and efficient hydrogen oxidation reaction electrocatalyst,namely RhxSy/C nanocatalyst supported on carbon,was prepared using a method of condensation reflux followed by low-tempera-ture calcination.The influence of calcination temperature on the catalytic performance of the electrocatalyst was investigated through physical characterization and electrochemical testing in 1 mol/L HCl.The results indicate that different calcination temperatures lead to different crystal phases in the RhxSy/C nanoparticles,thereby af-fecting the overall catalytic performance of the catalyst.The RhxSy/C catalyst prepared at a calcination tempera-ture of 350 ℃ possesses both certain hydrogen oxidation activity and good stability,maintaining 87.1％of its catalytic activity after 1 000 cycles of accelerated aging stability tests.关键词
氢氧化反应/酸性体系/硫化铑/稳定性Key words
hydrogen oxidation reaction/acid electrolyte/rhodium sulfide/stability分类
化学化工引用本文复制引用
初园园,赵若琛,周长剑,欧阳安鑫,谭小耀..碳载硫化铑催化剂在酸性体系中的氢氧化性能[J].天津工业大学学报,2025,44(2):43-50,8.基金项目
中国博士后科学基金项目(2020M680887) （2020M680887）
广东省燃料电池技术重点实验室开放基金(FC202223) （FC202223）
材料化学工程国家实验室课题项目(SKLMCE-22B02) （SKLMCE-22B02）
北京化工大学有机无机复合材料国家重点实验室开放基金(oic-202301004) （oic-202301004）
