大学化学2025，Vol.40Issue(4)：1-9,9.DOI:10.3866/PKU.DXHX202401007
固体推进剂中的维生素:中性大分子键合剂的可控合成
Vitamins in Solid Propellants:Controlled Synthesis of Neutral Macromolecular Bonding Agents
摘要
Abstract
Composite solid propellant,serving as the propulsion source of various solid engines in missiles and space vehicles,consist of solid particles(oxidizer and metal fuel)embedded in polymer matrices(binders).This experimental teaching module addresses the challenge of"dewetting"under load in solid propellants,where adhesive and filler separation occurs,compromising interfacial interactions.Through controlled radical polymerization,a well-defined neutral macromolecular bonding agent with controlled molecular weight and composition was synthesized.Its molecular structure was characterized using hydrogen nuclear magnetic spectroscopy and gel permeation chromatography system.This comprehensive experimental teaching not only deepens students'understanding of solid propellant technology,but also enhances their awareness of fundamental principles and methodologies in the field of cutting-edge polymer chemistry.Furthermore,it cultivates students'experimental operation skills,proficiency with sophisticated instrumentation,and capability in result analysis,bridging cutting-edge scientific research with the national imperative for talent development in critical technological domains.关键词
固体推进剂/大分子键合剂/可控自由基聚合/界面作用Key words
Solid propellant/Macromolecular bonding agent/Controlled radical polymerization/Interfacial interactions分类
社会科学引用本文复制引用
王振华,冯浩洋,邵晓阳,范文如..固体推进剂中的维生素:中性大分子键合剂的可控合成[J].大学化学,2025,40(4):1-9,9.基金项目
陕西省自然科学基础研究计划(2024JC-YBMS-294) （2024JC-YBMS-294）
西北工业大学研究生培养质量提升工程(05150-W210101) （05150-W210101）
