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悬浮聚合的改革探索:钙钛矿聚苯乙烯微珠的制备及其荧光稳定性能探究

闫泽祎 刘瑞涛 祁鑫禹 张玉香 孙璐璐 李相元 冯岸超

大学化学2025,Vol.40Issue(4):72-79,8.
大学化学2025,Vol.40Issue(4):72-79,8.DOI:10.12461/PKU.DXHX202405110

悬浮聚合的改革探索:钙钛矿聚苯乙烯微珠的制备及其荧光稳定性能探究

Exploration of Suspension Polymerization:Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads

闫泽祎 1刘瑞涛 1祁鑫禹 1张玉香 2孙璐璐 2李相元 3冯岸超4

作者信息

  • 1. 北京化工大学材料科学与工程学院先进弹性体材料研究中心,北京 100029
  • 2. 北京化工大学材料科学与工程学院先进弹性体材料研究中心,北京 100029||北京化工大学有机无机复合材料国家重点实验室,北京 100029
  • 3. 北京化工大学高分子科学与工程教学实验示范中心,北京 100029
  • 4. 北京化工大学材料科学与工程学院先进弹性体材料研究中心,北京 100029||北京化工大学有机无机复合材料国家重点实验室,北京 100029||北京化工大学高分子科学与工程教学实验示范中心,北京 100029
  • 折叠

摘要

Abstract

Organic-inorganic lead halide perovskites,known for their numerous outstanding optoelectronic properties,have garnered significant interest among researchers and hold promising applications across various advanced optoelectronic devices.However,perovskites suffer from poor stability and are highly susceptible to factors such as light,humidity,and polar solvents.Consequently,enhancing their fluorescence stability remains a focal point of current research.Building on the foundation of the undergraduate suspension polymerization experiment in polymer chemistry,this study introduces an undergraduate-led polymer science experiment titled"Preparation and Fluorescence Stability of Perovskite Quantum Dots Encapsulated in Polystyrene Microbeads".This strategy combines polymer and perovskite materials,encapsulating organic-inorganic perovskites within polystyrene microbeads using a swelling-shrinkage strategy to form hybrid fluorescent microbeads.This approach not only enhances the stability of the perovskite materials but also broadens the applications of products from polymer science experiments.Additionally,employing the swelling-shrinkage strategy as a vanguard for cutting-edge research in this field not only aids undergraduates in understanding experimental principles but also greatly stimulates their interest in scientific inquiry.By translating cutting-edge research into an experimental teaching reform model for undergraduate education,students'experimental design capabilities,innovation skills,and overall quality have been effectively developed.

关键词

高分子科学实验/钙钛矿荧光微珠/溶胀-收缩/自主设计实验

Key words

Polymer science experiment/Perovskite fluorescent microbeads/Swelling-shrinkage/Independent design experiment

分类

教育学

引用本文复制引用

闫泽祎,刘瑞涛,祁鑫禹,张玉香,孙璐璐,李相元,冯岸超..悬浮聚合的改革探索:钙钛矿聚苯乙烯微珠的制备及其荧光稳定性能探究[J].大学化学,2025,40(4):72-79,8.

基金项目

国家自然科学基金(ZK20220198) (ZK20220198)

北京科技新星计划(20230484260) (20230484260)

北京化工大学教改项目(2023BHDJGY62) (2023BHDJGY62)

大学化学

1000-8438

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