大学化学2025，Vol.40Issue(4)：277-281,5.DOI:10.12461/PKU.DXHX202407017
电化学促进硝基芳烃的脱硝基硼化和磺酰氟化反应
Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes
摘要
Abstract
Nitroarenes are widely utilized in organic synthesis and are a key topic in undergraduate organic chemistry curricula.However,efficient methods for denitrative transformations of nitroarenes under mild conditions remain limited.In recent years,green electrochemical synthesis has emerged as a promising approach for the selective C―N bond transformations of nitroarenes.This mini-review highlights recent advances in electrochemically facilitated denitrative transformations of nitroarenes,using reaction examples that are accessible to undergraduate students.These examples aim to expand students'understanding of denitrative processes,stimulate their interest in the field,enhance their learning experience,and enrich their knowledge base.关键词
硝基芳烃/脱硝基转化/电合成/芳基硼酸酯/芳基磺酰氟Key words
Nitroarenes/Denitrative transformation/Electrosynthesis/Aryl boronates/Aryl sulfonyl fluorides分类
社会科学引用本文复制引用
曹中艳,徐尤智,李梦华,肖霄,孔宪强,钱德云..电化学促进硝基芳烃的脱硝基硼化和磺酰氟化反应[J].大学化学,2025,40(4):277-281,5.基金项目
国家自然科学基金(22201062,22372015,22202021,22208302,22101250) （22201062,22372015,22202021,22208302,22101250）
河南大学校级教改项目(HDXJJG-2022-035) （HDXJJG-2022-035）
