化工进展2025，Vol.44Issue(5)：2577-2586,10.DOI:10.16085/j.issn.1000-6613.2025-0185
生物基呋喃二甲酸关键技术路线和产业发展现状
Advances in key technologies and industrial development of bio-based furandicarboxylic acid
摘要
Abstract
Driven by global carbon neutrality initiatives and the development of circular economy,bio-based materials are gradually emerging as significant alternatives to petroleum-based counterparts.Among these,2,5-furandicarboxylic acid(FDCA),with its rigid aromatic ring structure and exceptional physicochemical properties,is recognized as the most promising bio-based substitute for terephthalic acid,demonstrating broad application prospects in sustainable polymer materials.This review systematically analyzes mainstream FDCA production processes(including HMF,MMF/RMF,glucaric acid,and furfural/furoic acid routes),compares their economic viability and environmental benefits,and identifies the HMF pathway as the most industrially feasible approach currently available.However,key challenges persist,including poor stability of intermediate HMF,high energy consumption in separation processes,and limitations in catalytic system selectivity.By systematically organizing the technological routes,key steps,and industrialization processes of FDCA production through chemical methods,this study aims to provide theoretical references and technical support for promoting the efficient development and industrial upgrading of the FDCA sector.In the future,by focusing on high-value-added markets,developing novel HMF derivatization processes,advancing integrated chain production,and coordinating policies with industrial chain synergies,there is potential to overcome cost constraints and accelerate the industrialization process of FDCA.关键词
生物质/5-羟甲基糠醛/呋喃二甲酸/呋喃类新材料/产业化Key words
biomass/5-hydroxymethylfurfural/furandicarboxylic acid/furan-based new materials/industrialization分类
化学化工引用本文复制引用
乔凯,张震宇,马会霞,傅杰,周峰..生物基呋喃二甲酸关键技术路线和产业发展现状[J].化工进展,2025,44(5):2577-2586,10.基金项目
中国石化重大科技项目(O23001). （O23001）
