含能材料2025，Vol.33Issue(5)：448-454,7.DOI:10.11943/CJEM2024239
6-氨基-4-(三硝基甲基)-2-羰基-1H-1,3,5-三嗪的制备及性能
Synthesis and Properties of 6-Amino-4-(trinitromethyl)-2-carbonyl-1H-1,3,5-triazine
摘要
Abstract
A novel high-energy compound,6-Amino-4-(trinitromethyl)-2-carbonyl-1H-1,3,5-triazine,was synthesized in one step.The crystal structure of this compound was characterized by X-ray single crystal diffraction.Its structure and properties were characterized by 1H and 13C NMR,FT-IR and DSC.The detonation performance was calculated by EXPLO5.The sensitivity test-ing was performed according to the BAM standard method.The compound crystallizes in orthorhombic space group C 2/c,a=10.183(4)Å,b=9.388(3)Å,c=21.324(8)Å,V=2005.9(13)Å3,α=90°,β=100.246(10)°,γ=90°,Z=8.The calculated det-onation velocity and pressure for compound 1 are 8167 m·s-1 and 27.6 GPa,respectively,with measured impact sensitivity of 6 J and friction sensitivity of 210 N.关键词
高能量密度材料/三嗪类衍生物/合成/晶体结构/爆轰性能Key words
high energy density material/triazine derivative/synthesis/crystal structures/detonation performance分类
武器工业引用本文复制引用
张桐伟,许元刚,陆明..6-氨基-4-(三硝基甲基)-2-羰基-1H-1,3,5-三嗪的制备及性能[J].含能材料,2025,33(5):448-454,7.基金项目
国家自然科学基金(22475102) National Natural Science Foundation of China(No.22475102) （22475102）
