含能材料2025，Vol.33Issue(5)：523-553,31.DOI:10.11943/CJEM2025071
四唑多氮含能化合物的合成研究进展
Research Progress on the Synthesis of Tetrazole-based Nitrogen-rich Energetic Compounds
摘要
Abstract
Nitrogen-rich energetic compounds have attracted a great attention due to the high nitrogen content,high energy den-sity,good thermal stability,low sensitivity,and environmental friendliness.Among the stable azoles,tetrazole has the highest nitrogen content and energy level.Introducing diverse energetic rings or substituent groups into the tetrazole backbone offers a promising strategy for designing nitrogen-rich energetic materials with outstanding energetic performance and appropriate sensi-tivity.This review systematically summarizes the synthetic methods of nearly 200 tetrazole-based nitrogen-rich energetic com-pounds,categorizes these compounds based on the number of rings and connection modes,and highlights the physicochemical and detonation properties of representative energetic compounds.Finally,the future developments for these materials are pros-pected:creating tetrazole-based energetic compounds with new structures,promoting the engineering process of materials with promising applications,and conducting research on the application of compound 52(TKX-50).关键词
四唑/含能化合物/合成/爆轰性能/研究进展Key words
tetrazole/energetic compounds/synthesis/detonation performance/research progress分类
军事科技引用本文复制引用
李冬雪,崔杨瑞,阮可欣,李林杰,张雪飞,周钰婷,陆明,许元刚..四唑多氮含能化合物的合成研究进展[J].含能材料,2025,33(5):523-553,31.基金项目
国家自然科学基金(22135003,22475102),中国科协青年人才托举工程(YESS20210074),南京理工大学大学生创新创业训练计划资助 National Natural Science Foundation of China(Nos.22135003,22475102),Youth Talent Support Project of Chi-na Association for Science and Technology(YESS20210074),National Innovation and Entrepreneurship Training Program for College Students （22135003,22475102）
