塑料科技2025，Vol.53Issue(4)：156-160,5.DOI:10.15925/j.cnki.issn1005-3360.2025.04.028
HPLC法高效检测聚丙烯中抗氧剂1010与168的含量
Efficient Determination of Antioxidants 1010 and 168 in Polypropylene by HPLC
摘要
Abstract
A method for simultaneous determination of antioxidants 1010 and 168 in polypropylene(PP)resin was developed based on low temperature comminution-microwave extraction-high performance liquid chromatography.After the samples were crushed at low temperature and treated with microwave extraction at 80℃for 30 min,the antioxidant content of PP samples could be completely extracted.Then the antioxidant content of PP samples was determined by HPLC.The chromatographic conditions are as follows:ZORBAX SB-C18 column(5 μm,4.6 mm×150 mm);mobile phase:acetonitrile;flow rate:1.4 mL/min;detection wavelength:220 nm;column temperature:40℃;injection volume:20 μL.Under these conditions,the linear relationship of antioxidants 1010 and 168 was good in the range of 1.26～80.64 mg/L and 1.31～83.84 mg/L,respectively,and the correlation coefficient(R2)was not less than 0.999 7.The average recoveries of antioxidants 1010 and 168 were 91.05%and 95.18%,and the relative standard deviations(RSD)were 1.69%and 1.80%,respectively.The analytical method is simple,fast and accurate,and can be used to precisely regulate the content of antioxidants 1010 and 168 in PP system during production and processing.关键词
高效液相色谱法/微波萃取/低温粉碎/含量测定/质量控制Key words
High performance liquid chromatography/Microwave extraction/Low temperature grinding/Content determination/Quality control分类
化学引用本文复制引用
李涛,麻玉龙,曾化雨,王聚恒,杨康,张怡,黄晓枭..HPLC法高效检测聚丙烯中抗氧剂1010与168的含量[J].塑料科技,2025,53(4):156-160,5.基金项目
贵州省科学院青年基金(黔科院J字[2024]3号) （黔科院J字[2024]3号）
贵州省重大科技成果转化项目(黔科合成果[2024]重大002) （黔科合成果[2024]重大002）
贵州省冶金化工研究所科研发展基金(黔科冶化字KF[2023]01号) （黔科冶化字KF[2023]01号）
贵州省基础研究计划(自然科学)青年引导项目(黔科合基础-[2024]青年373) （自然科学）
贵州省科学院青年基金(黔科院J字[2025]18号) （黔科院J字[2025]18号）
贵州省科技支撑计划(黔科合支撑[2025]一般010) （黔科合支撑[2025]一般010）
贵州省冶金化工研究所科研发展基金(黔科冶化字KF[2025]02号) （黔科冶化字KF[2025]02号）
