中南大学学报（自然科学版）2025，Vol.56Issue(4)：1639-1647,9.DOI:10.11817/j.issn.1672-7207.2025.04.032
等离子体协同催化分解甲醇制氢研究
Synergistic catalytic decomposition of methanol for hydrogen production by plasma
摘要
Abstract
In order to investigate the effects of dielectric barrier discharge plasma technology and catalyst on methanol hydrogen production,a double-layer dielectric barrier discharge reactor with nanosecond pulsed discharge excitation was designed to investigate the effects of different power supply parameters on the kinetics of methanol hydrogen decomposition,and experimental data were obtained on the concentration of species in methanol hydrogen decomposition under the action of plasma,and it was found that both increasing voltage and frequency had a positive effect on the efficiency of methanol hydrogen decomposition,and the effect of voltage was more obvious.On this basis,the hydrogen yield and product selectivity of hydrogen production from methanol decomposition with plasma,catalytic and plasma co-catalytic effects were compared.The results show that the hydrogen selectivity is lower with the plasma alone,accompanied by the generation of by-products,such as methane and ethane,etc.;the catalyst alone results in fewer product species but the hydrogen production efficiency is too low;the hydrogen production rate in the synergistic plasma catalytic mode is higher than those of the two catalysts alone.关键词
制氢/甲醇/介质阻挡放电/非平衡等离子体Key words
hydrogen production/methanol/dielectric barrier discharge/nonequilibrium plasma分类
能源科技引用本文复制引用
李淑铭,胡二江,殷阁媛,黄佐华..等离子体协同催化分解甲醇制氢研究[J].中南大学学报（自然科学版）,2025,56(4):1639-1647,9.基金项目
国家自然科学基金资助项目(52106182)(Project(52106182)supported by the National Natural Science Foundation of China) （52106182）
