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化学强化的二硅酸锂-透锂长石微晶玻璃的化学耐久性

胡伟 尹勇明 孟鸿

材料科学与工程学报2025,Vol.43Issue(2):169-177,9.
材料科学与工程学报2025,Vol.43Issue(2):169-177,9.DOI:10.14136/j.cnki.issn1673-2812.2025.02.001

化学强化的二硅酸锂-透锂长石微晶玻璃的化学耐久性

Chemical Durability of Chemical Strengthened Lithium Disilicate-petalite Glass-ceramics

胡伟 1尹勇明 2孟鸿1

作者信息

  • 1. 北京大学深圳研究生院新材料学院,广东 深圳 518055
  • 2. 深圳北理莫斯科大学,广东 深圳 518172
  • 折叠

摘要

Abstract

Lithium disilicate-petalite glass-ceramic was prepared and chemically strengthened.The corrosion mechanism of glass in acid &alkaline conditions was studied by means of XRD and SEM.The experimental results show that the residual glass phase of lithium disilicate-petalite glass-ceramics is corroded first,and then the crystals are exposed.H+replaces Li in petalite,and the product HAlSi4O10 accumulates on the surface of the glass-ceramics.This experiment further explored the effect of glass formulation and the strengthening process on chemical durability.The results showed that reducing the content of Na2O in the base glass,increasing the content of ZrO2 and K2O,and adding a little LiNO3(0.03%)to the ion exchange salt bath could significantly improve the chemical durability of lithium disilicate-petalite glass-ceramics.

关键词

锂铝硅微晶玻璃/二硅酸锂/透锂长石/化学耐久性

Key words

Li2O-Al2O3-SiO2 glass-ceramics/Lithium disilicate/Petalite/Chemical durability

分类

化学工程

引用本文复制引用

胡伟,尹勇明,孟鸿..化学强化的二硅酸锂-透锂长石微晶玻璃的化学耐久性[J].材料科学与工程学报,2025,43(2):169-177,9.

基金项目

国家自然科学基金面上项目(51873002) (51873002)

广东省基础与应用基础研究基金项目(2020B1515120029) (2020B1515120029)

材料科学与工程学报

OA北大核心

1673-2812

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