应用化学2025，Vol.42Issue(5)：621-641,21.DOI:10.19894/j.issn.1000-0518.240314
Gemini表面活性剂的制备、组装及应用研究进展
Research Progress in the Synthesis,Assembly and Applications of Gemini Surfactants
摘要
Abstract
Gemini surfactant is a type of surfactant with a special structure,which contains two hydrophobic groups,two hydrophilic groups,and one linking group.Compared with traditional surfactants,Gemini surfactants have attracted great attention due to their advantages of better surface activity,lower critical micelle concentration and Kraff point,good emulsifying ability,foam performance,and excellent wetting performance,which lead them to play an important role in daily life,industrial production,high-end manufacturing and other fields.In this review,the synthesis of Gemini surfactants with different structures are introduced,followed by the aggregate structures of Gemini surfactants under different conditions and the mutual transformation between aggregate structures as well as their applications in different fields such as petroleum exploration,synthetic templates,corrosion inhibitors,drug carriers,integrated circuit manufacturing,etc.In the end,future research directions on the design of novel Gemini surfactants and the application in advanced semiconductor chips manufacturing are proposed.关键词
Gemini表面活性剂/合成/聚集体/组装/应用Key words
Gemini surfactants/Synthesis/Aggregates/Assembly/Application分类
化学引用本文复制引用
张之钧,邢攸美,吴振,方伟华,尹云舰,王国杰..Gemini表面活性剂的制备、组装及应用研究进展[J].应用化学,2025,42(5):621-641,21.基金项目
国家重点基础研究发展规划(No.2009CB724100)、浙江省科技计划项目(No.2022C01080)和国家自然科学基金(No.51373025)资助 Supported by the National Key Basic Research Development Plan(No.2009CB724100),Zhejiang Province Science and Technology Project(No.2022C01080)and the National Natural Science Foundation of China(No.51373025) （No.2009CB724100）
