常州大学学报（自然科学版）2025，Vol.37Issue(3)：10-15,6.DOI:10.3969/j.issn.2095-0411.2025.03.002
苯并[1,2-b:4,5-b']二噻吩衍生物的制备及其光学性能研究
Preparation and optical properties of benzo[1,2-b:4,5-b']dithiophene derivatives
摘要
Abstract
Compounds 4,4'-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophene-2,6-diyl)bis(2,3,5,6-tetrafluorobenzonitrile)(TBDBT)and 4,4'-(4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b']dithiophene-2,6-diyl)bis(2,3,5,6-tetrafluoroben-zonitrile)(OBDBT)containing conjugated benzo[1,2-b:4,5-b']dithiophene were designed and synthesized by the classical Stille coupling reaction.Theoretical calculations show that the conjugation of compound OBDBT increases when 2-ethylhexyloxy is introduced to the benzo[1,2-b:4,5-b']di-thiophene skeleton,which emits strong red light,and the fluorescence quantum yield reaches 81％.Therefore,substituents can be used to adjust the conjugation of benzo[1,2-b:4,5-b']dithiophene derivatives to achieve the preparation of red-light materials with high fluorescence quantum yield.关键词
苯并[1,2-b:4,5-b']二噻吩/红光/荧光Key words
benzo[1,2-b:4,5-b']dithiophene/red light/fluorescence分类
化学引用本文复制引用
顾培洋,郭文秀,周仕元..苯并[1,2-b:4,5-b']二噻吩衍生物的制备及其光学性能研究[J].常州大学学报（自然科学版）,2025,37(3):10-15,6.基金项目
常州市领军型创新人才引进培育资助项目(CQ20220111). （CQ20220111）
