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包装用可生物降解聚酯材料的制备及性能研究

李鹏鹏 李武伟

日用化学工业(中英文)2025,Vol.55Issue(5):625-632,8.
日用化学工业(中英文)2025,Vol.55Issue(5):625-632,8.DOI:10.3969/j.issn.2097-2806.2025.05.011

包装用可生物降解聚酯材料的制备及性能研究

Preparation and properties of biodegradable polyester materials for packaging

李鹏鹏 1李武伟2

作者信息

  • 1. 郑州信息工程职业学院,河南 郑州 450121
  • 2. 新乡学院,河南 新乡 453003
  • 折叠

摘要

Abstract

In this paper,polylactic acid/polyester system was prepared by melt blending of polyethylene terephthalate(PET)and polylactic acid(PLA)with tetrabutyl titanate as solubilizer.The effects of the proportion of PLA on the micromorphology,thermal stability,mechanical properties and biodegradability of the system were studied.The results show that the blends formed by melt blending of PET and PLA have good compatibility without obvious interface and agglomeration.The thermal stability of polylactic acid/polyester blend is improved with the increase of PLA mass fraction,and the carbon residue rate decreases with the increase of PLA mass fraction.The tensile strength and fracture elongation of PLA blend with 30%mass fraction reach the maximum value of 55.1 MPa and 16.2%,which are 39.50%and 48.62%higher than that of the pure PET,respectively.The notch impact strength is 27.9 kJ/m2,which is 108.21%higher than that of the pure PET.The corresponding hardness is 92 HR.The biodegradation rate of polylactic acid/polyester blend in buffer increases with the increase of PLA mass fraction.At 28 d of degradation,the notch impact strength of the blend with 30%PLA mass fraction is 27.9 kJ/m2,indicating the best mechanical properties.

关键词

聚对苯二甲酸乙二醇酯/聚乳酸/熔融共混/生物降解/热稳定性

Key words

polyethylene terephthalate/polylactic acid/melt blending/biodegradation/thermal stability

分类

化学化工

引用本文复制引用

李鹏鹏,李武伟..包装用可生物降解聚酯材料的制备及性能研究[J].日用化学工业(中英文),2025,55(5):625-632,8.

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