铀矿冶2025，Vol.44Issue(2)：84-88,5.DOI:10.13426/j.cnki.yky.2024.08.07
热催化分解13CF4制备13CO2技术研究
Research of Thermal Catalytic Decomposition of 13CF4 to 13CO2
罗加强 1李梅芳 1杨建平 1王晓光1
作者信息
- 1. 中核燃料沧州有限公司,河北沧州 061000
- 折叠
摘要
Abstract
In order to solve the problems of microwave plasma decomposition of 13CF4,such as com-plex operation process,harsh decomposition conditions and easy corrosion of reaction tubes,the ther-mal catalytic decomposition of 13CF4 to produce 13CO2 was studied.Under the condition of anhydrous and high temperature,13CF4 was decomposed into 13CO2 by gas-solid reaction between 13CF4 and solid defluorination agent,using γ-Al2O3 as solid defluorination agent,meanwhile,the metal oxide in the defluorination agent is converted into metal fluoride.The results show that when the flow rate of re-action gas is 120 mL/min,the loading amount of catalyst is more than 60 g,the content of O2 in feed gas mixture is more than 50％,and the temperature of high temperature tubular furnace is 900 ℃,the conversion of γ-Al2O3 catalyst to 13CF4 gas is over 90％,which has good catalytic decomposition per-formance and can realize continuous catalysis and decomposition.The catalytic decomposition process has the advantages of simple process,convenient operation and very high carbon yield,and can be used in industrial production.关键词
γ型Al2O3/催化/分解/13CF4/13CO2Key words
γ-Al2O3/catalytic/decomposition/13CF4/13CO2分类
能源科技引用本文复制引用
罗加强,李梅芳,杨建平,王晓光..热催化分解13CF4制备13CO2技术研究[J].铀矿冶,2025,44(2):84-88,5.
