化工学报2025，Vol.76Issue(5)：2011-2025,15.DOI:10.11949/0438-1157.20240819
推进MOF产业化应用:宏量制备与成型
Promoting industrial application of MOF:scale-up preparation and shaping
摘要
Abstract
Metal-organic frameworks(MOF)are a new type of porous materials constructed by metal ions or metal clusters with organic ligands through coordination bonds.They show advantages such as diverse structures,high specific surface area,high porosity,and diversified regulation of structures and properties.In recent years,MOF has gradually attracted attention in different fields such as adsorption/separation,catalysis,and sensing.However,the scale-up preparation of MOF faces many challenges,including stringent synthesis conditions,prolonged reaction times,reduced yields,and increased costs.Therefore,researchers are exploring various new synthesis methods,such as hydrothermal/solvothermal,rapid room temperature synthesis,solvent reflux,base-assisted,mechanochemical,electrochemical,microwave-assisted,spray-drying,ultrasonic,dry gel conversion,and accelerated aging methods.Thus,the methods for scale-up preparation of MOF are reviewed,and factors like cost,environmental impact,safety,and practical feasibility are assessed.Additionally,the article will briefly discuss advances in MOF shaping technologies to accelerate progress in those fields.The future challenges and opportunities for scale-up preparation and shaping of MOF materials are envisioned.关键词
金属-有机框架/化工新材料/宏量制备/加工成型/工业应用/制备/安全/多孔介质Key words
metal-organic frameworks(MOF)/chemical new materials/scale-up preparation/material forming/industrial application/preparation/safety/porous medium分类
化学工程引用本文复制引用
安昊天,韩章烨,陆慕瑶,周阿武,李建荣..推进MOF产业化应用:宏量制备与成型[J].化工学报,2025,76(5):2011-2025,15.基金项目
国家自然科学基金项目(22225803,22308011) （22225803,22308011）
