化工学报2025，Vol.76Issue(5)：2026-2041,16.DOI:10.11949/0438-1157.20241221
蒸气相辅助法制备MOF基材料的研究进展
Research progress of MOF preparation by steam-assisted method
摘要
Abstract
Metal-organic framework materials(MOFs)have shown great potential in various applications,including gas adsorption and separation,catalysis,and sensing due to their high specific surface area and porosity,adjustable pore sizes,and diverse structures.However,the synthesis of traditional MOF materials is mainly based on solvothermal method,which not only consumes a large amount of high-value organic solvents,but also has high energy consumption,low yield,and difficult waste liquid treatment in the production process,which does not meet the requirements of green development of chemical industry.The steam-assisted synthesis,which has the advantages of small solvent dosage,fewer reaction processes and shorter cycle time,has received extensive attention in the synthesis and modification of MOF materials in recent years,and it is expected to provide a new green and efficient pathway for the synthesis of MOF materials.This paper reviews the research advancements of MOF prepared by steam-assisted method,overviews the research progress of this method in the synthesis and modification of MOF materials.Additionally,the prospective developments of this synthesis method are discussed.关键词
金属有机骨架材料/蒸气辅助/合成/经济/改性/绿色Key words
metal-organic framework materials/steam-assisted/synthesis/economic/modification/green分类
化学工程引用本文复制引用
张冰,李建惠,马欣蓉,陈杨,李晋平,李立博..蒸气相辅助法制备MOF基材料的研究进展[J].化工学报,2025,76(5):2026-2041,16.基金项目
国家重点研发计划项目(2022YFB3806800) （2022YFB3806800）
国家自然科学基金项目(22278287,22278288,22090062) （22278287,22278288,22090062）
