化工学报2025，Vol.76Issue(5)：2070-2086,17.DOI:10.11949/0438-1157.20241225
以蒸气加工法制备和修饰金属-有机框架膜
Vapor-phase synthesis and post-synthetic modification of metal-organic framework membranes
摘要
Abstract
Metal-organic frameworks(MOFs)are a class of highly ordered porous materials composed of metal ions or metal ion clusters coordinated with organic ligands.MOF membranes have been widely used in the chemical separation.High-efficient synthetic and post-synthetic modification methods help to obtain continouous,defect-free and structurally diverse MOF membranes.Compared with traditional liquid-phase synthesis methods,vapor processing is a high-effcient and environmentally friendly method.Using a vapor processing method,we can cut down the consumption of solvents and precursors,avoid the competitive nucleation in a bulk solution,reduce the risk of membrane cracking as a result of the removal of solvent molecules in the post-treatment of membranes.In this review,we summarize the research progress in direct synthesis and post-synthetic modifications of MOF membranes by vapor processing,and highlight the achivenments in regulation and optimization of membrane performances by vapor processing.Finally,an outlook on future directions of vapor processing and its potential for large-scale production of MOF membranes were provided.关键词
金属-有机框架/膜/蒸气加工/直接合成/合成后修饰/分离/渗透率/选择性Key words
metal-organic frameworks/membrane/vapor processing/direct synthesis/post-synthetic modification/separation/permeance/selectivity分类
化学工程引用本文复制引用
张耀辉,班宇杰,杨维慎..以蒸气加工法制备和修饰金属-有机框架膜[J].化工学报,2025,76(5):2070-2086,17.基金项目
国家自然科学基金项目(22090063) （22090063）
能源催化转化全国重点实验室开放合作基金项目(2024SKL-A-010) （2024SKL-A-010）
辽宁省科技计划联合计划(重点研发计划)项目(2023JH2/101800053) （重点研发计划）
大连化学物理研究所创新基金项目(DICP I202311) （DICP I202311）
中国科学院青年创新促进会项目(2021179) （2021179）
