化工环保2025，Vol.45Issue(3)：363-370,8.DOI:10.3969/j.issn.1006-1878.2025.03.007
Fe-B/N-C单原子催化剂活化PMS处理焦化废水
Treatment of coking wastewater by Fe-B/N-C single-atom catalyst with PMS activation
摘要
Abstract
The Fe-B/N-C single-atom catalyst(SAC)was prepared by a one-pot synthesis method for the removal of pollutants in coking wastewater via peroxymonosulfate(PMS)activation.The catalyst contained 3.69％(w)Fe loading,and doping with boron did not alter the catalyst's morphology.The Fe,B,N,and C elements were well-dispersed on the surface of Fe-B/N-C.The Fe-B/N-C/PMS system demonstrated excellent catalytic performance,achieving 100％phenol removal within 10 min and 75.8％TOC removal within 30 min,when the Fe-B/N-C dosage was 0.5 g/L and PMS concentration was 2.0 g/L.Compared with the PMS-only and Fe-N-C/PMS systems,the Fe-B/N-C/PMS system exhibited superior performance in removing fluorescent dissolved organic matter(FDOM)from coking wastewater.After 30 min reaction,the fluorescence intensity of the wastewater decreased by 84.8％,with protein,tryptophan,and dissolved microbial metabolite removal reaching 80.9％,60.8％,and 81.4％,respectively.关键词
类芬顿反应/过一硫酸盐/单原子催化剂/杂原子掺杂/苯酚Key words
Fenton-like reaction/peroxymonosulfate/single-atom catalyst/heteroatom doping/phenol分类
环境科学引用本文复制引用
王建,刘宇琪,韩世豪,杨少霞..Fe-B/N-C单原子催化剂活化PMS处理焦化废水[J].化工环保,2025,45(3):363-370,8.基金项目
国家自然科学基金联合基金项目(U22A20241). （U22A20241）
