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酸碱处理对自来水厂含铝污泥浓缩及脱水性能的影响

王旋 戴子承 马平安 白昊 崔红军 张建锋

化工环保2025,Vol.45Issue(3):371-376,6.
化工环保2025,Vol.45Issue(3):371-376,6.DOI:10.3969/j.issn.1006-1878.2025.03.008

酸碱处理对自来水厂含铝污泥浓缩及脱水性能的影响

Effect of acidification and alkalization treatment on thickening and dewatering properties of aluminum sludge from water treatment plants

王旋 1戴子承 2马平安 3白昊 3崔红军 3张建锋4

作者信息

  • 1. 西安水务(集团)有限责任公司,陕西 西安 710061
  • 2. 中国市政工程中南设计研究总院有限公司,湖北 武汉 430010
  • 3. 西安水务(集团)规划设计研究院有限公司,陕西 西安 710061
  • 4. 西安建筑科技大学 环境与市政工程学院,陕西 西安 710055
  • 折叠

摘要

Abstract

The polyaluminum chloride(PAC)sludge produced in a water treatment plant was used to investigate the settling,thickening and dewatering properties of the sludge after acidification/alkalization treatment.The moisture distribution features of the sludge were analyzed by thermogravimetric-differential scanning calorimetry(TG-DSC)method to reveal the dewatering mechanism.The results show that after reaction for 2 h at pH 2.0 or 12.0,the Al dissolution rates from sludge were(73.24±7.84)%or(20.19±3.52)%,respectively.Compared to alkali treatment,the acid treatment is more conducive to Al dissolution.The settling velocity of the muddy liquid surface is 0.39 cm/min for raw sludge,2.16 cm/min for the acid-treated,and 0.91 cm/min for the alkali-treated,respectively.Compared with the raw sludge,the acid-treated sludge has seen a reduction rate in the sludge volume index(SVI)ranging from 61.5%to 90.7%,with an average of 73.7%,and that of the alkali-treated sludge ranging from 11.3%to 63.5%,with an average of 38.2%.Under the rotating velocity of 20 000 r/min for 40 min,the moisture content of the acid-treated sludge and the alkali-treated sludge decreases from 96.4%to 69.1%and 98.9%to 78.1%,respectively.After acidification treatment,the sludge has seen a reduction in the organic content and the surface zeta potential in the particle surface,with weaker electrostatic repulsion,more uniform particle size distribution,and denser particle structure.Dewatering properties are then effective improved.

关键词

含铝污泥/酸化处理/沉降及浓缩/脱水性能

Key words

aluminum sludge/acidification/settling and thickening/dewatering property

分类

资源环境

引用本文复制引用

王旋,戴子承,马平安,白昊,崔红军,张建锋..酸碱处理对自来水厂含铝污泥浓缩及脱水性能的影响[J].化工环保,2025,45(3):371-376,6.

基金项目

陕西省科技创新团队项目(2022TD-34). (2022TD-34)

化工环保

OA北大核心

1006-1878

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