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甘油与尿素合成甘油碳酸酯催化剂研究进展

王于华 李洪广 丁亮 寇永利 戚文博 赵宁

燃料化学学报(中英文)2025,Vol.53Issue(6):964-982,19.
燃料化学学报(中英文)2025,Vol.53Issue(6):964-982,19.DOI:10.1016/S1872-5813(25)60538-X

甘油与尿素合成甘油碳酸酯催化剂研究进展

Research progress of catalysts for synthesis of glycerol carbonate form glycerol and urea

王于华 1李洪广 2丁亮 3寇永利 2戚文博 2赵宁4

作者信息

  • 1. 西安培华学院,陕西西安 710125
  • 2. 陕西煤业化工技术研究院有限责任公司,陕西西安 710100
  • 3. 西安石油大学化学化工学院,陕西西安 710065
  • 4. 中国科学院山西煤炭化学研究所,山西太原 030001
  • 折叠

摘要

Abstract

Transformation of urea and glycerol to glycerol carbonate is an environmental friendly and economical process.Catalysts play an indispensable role in the process.Although many catalysts have been developed,the performance of the catalysts still cannot meet the needs of industrialization.In this paper,research progress of the homogeneous and heterogeneous catalysts of the reaction over the past 20 years were reviewed systematically.According to the types and active centers of catalysts,the catalysts were classified systematically and analyzed in detail.The typical reaction mechanisms were also summarized.The research and development direction of catalysts is made more explicit through systematic classification and mechanism analysis.The article reveals more novel catalysts have been designed and used for the reaction,such as mixed metal oxides with special structures,solid wastes and non-metallic materials.This work summarized the current state of research and prospected possible routes for design of novel catalysts.It is hoped that this review can provide some references for developing efficient catalysts.

关键词

甘油碳酸酯/甘油/尿素/催化剂

Key words

glycerol carbonate/glycerol/urea/catalysts

分类

化学化工

引用本文复制引用

王于华,李洪广,丁亮,寇永利,戚文博,赵宁..甘油与尿素合成甘油碳酸酯催化剂研究进展[J].燃料化学学报(中英文),2025,53(6):964-982,19.

基金项目

The project was supported by Fundamental Research Program of Shanxi Province(202203021221303). (202203021221303)

燃料化学学报(中英文)

OA北大核心

2097-213X

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