含能材料2025，Vol.33Issue(6)：557-564,8.DOI:10.11943/CJEM2025012
4,4,8,8-四硝基-2,6-二氧杂金刚烷的合成及表征
Synthesis and Characterization of 4,4,8,8-Tetranitro-2,6-dioxaadamantane
摘要
Abstract
A novel cage-like energetic compound,4,4,8,8-tetranitro-2,6-dioxaadamantane,was synthesized via four steps in-volving oxidative cyclization,oxidation,oximation and gem-dinitration by using 9-oxabicyclo[3.3.1]nona-2,6-diene as raw ma-terial.Its structure was characterized by nuclear magnetic resonance(NMR),Fourier transform infrared spectroscopy(FT-IR)and elemental analysis(EA),and single crystal X-ray diffraction(SC-XRD)was adopted to further confirm its crystal structure.The thermal stability was investigated by differential scanning calorimetry-thermogravimetry(DSC-TG)analysis,and detonation parameters were predicted by EXPLO5.Results show that 4,4,8,8-tetranitro-2,6-dioxaadamantane has a crystal density of 1.75 g·cm-3 and belongs to monoclinic system,space groups P21/c.Its thermal decomposition temperature is 190.6℃,theoreti-cal detonation velocity is 7705 m·s-1,and detonation pressure is 25.75 GPa.关键词
氧杂金刚烷/偕二硝基/含能笼状化合物/合成/热稳定性Key words
oxaazaadamantane/gem-dinitration/energetic cage-like compound/synthesis/thermal stability分类
武器工业引用本文复制引用
李欢,周琪,侯天骄,王桂香,罗军..4,4,8,8-四硝基-2,6-二氧杂金刚烷的合成及表征[J].含能材料,2025,33(6):557-564,8.基金项目
国家自然科学基金(22075144) National Natural Science Foundation of China(No.22075144) （22075144）
