硫酸法钛白粉酸解渣综合利用试验研究OA
Experimental study on comprehensive utilization of sulfuric acid method titanium dioxide acid digestion waste
硫酸法生产钛白粉工艺除了会产生大量酸性废水外,还会产生大量酸解渣.酸解渣的大量堆积,不仅会造成资源浪费,还会对环境产生污染.本文以硫酸法钛白粉酸解渣为研究对象,提出了"磁选-NaOH浸出"新工艺,考察了磁感应强度、脉动冲次、磁介质丝径等对磁选法回收钛的影响,以及浸出时间、浸出温度、液固比等对浸出效果的影响.结果表明:通过"1粗1精1扫"的磁选流程可以得到产率为37.31%、TiO2品位为50.39%、回收率为87.64%的精矿产品;磁选精矿可代替钛铁矿作为硫酸法生产钛白粉的原料,磁选尾矿经预处理后可作为硅源进行碱浸,在最佳条件下可制得模数为2.38的水玻璃.研究成果为硫酸法钛白粉酸解渣的综合利用提供了一条新思路.
The sulfuric acid process for producing titanium dioxide not only generates a large amount of acidic wastewater,but also produces a large amount of acid slag.The large accumulation of acid slag not only causes resource waste,but also pollutes the environment.This paper took the sulfuric acid method of titanium dioxide acid slag as the research object,proposed the new process of"magnetic separation-NaOH leaching",and investigated the effects of magnetic induction intensity,pulsation stroke,magnetic medium wire diameter,etc.on the recovery of titanium by magnetic separation method,as well as the effects of leaching time,leaching temperature,liquid-solid ratio,etc.on leaching efficiency.The results show that the concentrate product with the yield of 37.31%,TiO2 grade of 50.39%,and recovery rate of 87.64%can be obtained through the magnetic separation process of"one coarse,one fine and one sweep";Magnetic separation concentrate can replace ilmenite as the raw material for the production of titanium dioxide by sulfuric acid method.After pretreatment,magnetic separation tailings can be used as the silicon source for alkali leaching,and under optimal conditions,water glass with a modulus of 2.38 can be produced.The research results pro-vide a new idea for the comprehensive utilization of sulfuric acid method titanium dioxide acid slag.
王蓓琳;高利坤;饶兵;张青松;陆一铭
昆明理工大学 国土资源工程学院,云南 昆明 650093昆明理工大学 国土资源工程学院,云南 昆明 650093昆明理工大学 国土资源工程学院,云南 昆明 650093昆明理工大学 国土资源工程学院,云南 昆明 650093昆明理工大学 国土资源工程学院,云南 昆明 650093
环境科学
硫酸法钛白粉酸解渣磁选浸出水玻璃预处理综合利用
sulfuric acid methodacidolysis slag of titanium dioxidemagnetic separationleachingwater glasspretreatmentcomprehensive utilization
《化工矿物与加工》 2025 (6)
18-28,11
云南省科技厅科技计划项目(202401AU070146).
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