近红外光谱法测定航煤烟点的研究OA
Measurement of Smoke Point in Kerosene by Near-infrared Spectroscopy
主要通过研究近红外光谱分析技术实现了航煤烟点指标的简便、快速、无损检测.以航空煤油为例建立模型,采集78 个样品,基于偏最小二乘法进行多元统计分析,采用不同预处理方法,并对模型进行了交叉检验.结果表明,二阶导数产生较好的预测效果,相关系数(R)值较高 0.9252,模型的RPD 值 3.33,RMSECV 数值较小为0.093,表明所建模型的稳健性较好,可以作为快速测定航煤烟点含量的一种无损方法.
Smoke point in kerosene is one of the important indexes to reflect the performance of kerosene,In this paper,a simple,fast and nonde-structive detection of smoke point is mainly achieved by the Near-infrared Spectroscopy,the model can be built under taking kerosene for in-stance,78 samples were collected,and multivariate statistical analysis was carried out based on partial least square method.The calibrations of the smoke point in kerosene were also performed by different pretreatment methods.The results showed that the second derivative produced a bet-ter prediction,The correction coefficient(R),the Ratio of standard deviation and standard error of prediction(RPD),the Root Mean Squared Er-ror of Cross-Validation(RMSECV)were 0.9252,3.33,and 0.093.The results showed that the prediction accuracy of the model was higher,and this model could determine the smoke point in kerosene used as a rapid and lossless method to detect the quality of kerosene.
焦惠
中海油惠州石化有限公司,广东 惠州 516081
石油、天然气工程
近红外光谱航空煤油烟点二阶导数统计方法偏最小二乘法
Near-infrared SpectroscopyKerosenethe Smoke PointSecond DerivativeStatistical TechniquesPartial Least Square Method
《云南化工》 2025 (6)
106-109,4
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