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化学气相沉积法生长石墨烯的现状及展望

黄子翀 刘伟林 李骏 蒋宇 袁国文 高力波

新型炭材料(中英文)2025,Vol.40Issue(3):457-476,20.
新型炭材料(中英文)2025,Vol.40Issue(3):457-476,20.DOI:10.1016/S1872-5805(25)60991-7

化学气相沉积法生长石墨烯的现状及展望

Current status and prospect of graphene growth by chemical vapor deposition

黄子翀 1刘伟林 1李骏 1蒋宇 1袁国文 1高力波2

作者信息

  • 1. 南京大学 物理学院,固体微结构物理国家重点实验室,人工微结构科学与技术协同创新中心,江苏 南京 210093
  • 2. 南京大学 物理学院,固体微结构物理国家重点实验室,人工微结构科学与技术协同创新中心,江苏 南京 210093||湖南大学 材料科学与工程学院,湖南 长沙 410082
  • 折叠

摘要

Abstract

Graphene has attracted widespread attention since 2004 because of its outstanding physical and chemical properties.Among its various synthesis methods,chemical vapor deposition(CVD)has emerged as the dominant approach for producing high-quality graphene films,owing to its high controllability,low cost,and scalability.This review systematically summarizes the technological development of graphene synthesis by CVD,with a focus on recent progress in key areas such as single-crys-tal graphene growth,surface flatness control,precise control of the number of layers,and efficient large-scale production.Stud-ies have shown that strategies such as substrate design,proton-assisted decoupling techniques,and oxygen-assisted methods have enabled the wafer-scale synthesis of single-crystal graphene with electrical properties comparable to that of mechanically exfoliated samples.However,several technical challenges remain,including direct growth on insulating substrates,high-qual-ity synthesis at low-temperatures,and the dynamic control of defects.Looking ahead,the integration of novel carbon sources,multifunctional fabrication processes,and roll-to-roll industrial production is expected to advance the practical use of graphene in fields such as flexible electronics and energy storage.

关键词

石墨烯/二维材料/化学气相沉积/形貌调控/规模化生长

Key words

Graphene/Two-dimensional materials/Chemical vapor deposition/Morphological control/Large-scale growth

分类

化学化工

引用本文复制引用

黄子翀,刘伟林,李骏,蒋宇,袁国文,高力波..化学气相沉积法生长石墨烯的现状及展望[J].新型炭材料(中英文),2025,40(3):457-476,20.

基金项目

感谢国家自然科学基金(52425203)、江苏省自然科学基金(BK20240008、BK20241252、BK20233001)、小米基金会、南京大学固体微结构物理国家重点实验室基金(M35041)和南京大学队伍建设启动基金(14912249). National Natural Science Foundation of China(52425203),Natural Science Foundation of Jiangsu Province(BK20240008,BK20241252,BK20233001),Xiaomi Foundation,Fund of laboratory of Solid State Microstruc-tures of Nanjing University(M35041)and Fund of Nanjing University Faculty Development(14912249). (52425203)

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