新型炭材料(中英文)2025,Vol.40Issue(3):457-476,20.DOI:10.1016/S1872-5805(25)60991-7
化学气相沉积法生长石墨烯的现状及展望
Current status and prospect of graphene growth by chemical vapor deposition
摘要
Abstract
Graphene has attracted widespread attention since 2004 because of its outstanding physical and chemical properties.Among its various synthesis methods,chemical vapor deposition(CVD)has emerged as the dominant approach for producing high-quality graphene films,owing to its high controllability,low cost,and scalability.This review systematically summarizes the technological development of graphene synthesis by CVD,with a focus on recent progress in key areas such as single-crys-tal graphene growth,surface flatness control,precise control of the number of layers,and efficient large-scale production.Stud-ies have shown that strategies such as substrate design,proton-assisted decoupling techniques,and oxygen-assisted methods have enabled the wafer-scale synthesis of single-crystal graphene with electrical properties comparable to that of mechanically exfoliated samples.However,several technical challenges remain,including direct growth on insulating substrates,high-qual-ity synthesis at low-temperatures,and the dynamic control of defects.Looking ahead,the integration of novel carbon sources,multifunctional fabrication processes,and roll-to-roll industrial production is expected to advance the practical use of graphene in fields such as flexible electronics and energy storage.关键词
石墨烯/二维材料/化学气相沉积/形貌调控/规模化生长Key words
Graphene/Two-dimensional materials/Chemical vapor deposition/Morphological control/Large-scale growth分类
化学化工引用本文复制引用
黄子翀,刘伟林,李骏,蒋宇,袁国文,高力波..化学气相沉积法生长石墨烯的现状及展望[J].新型炭材料(中英文),2025,40(3):457-476,20.基金项目
感谢国家自然科学基金(52425203)、江苏省自然科学基金(BK20240008、BK20241252、BK20233001)、小米基金会、南京大学固体微结构物理国家重点实验室基金(M35041)和南京大学队伍建设启动基金(14912249). National Natural Science Foundation of China(52425203),Natural Science Foundation of Jiangsu Province(BK20240008,BK20241252,BK20233001),Xiaomi Foundation,Fund of laboratory of Solid State Microstruc-tures of Nanjing University(M35041)and Fund of Nanjing University Faculty Development(14912249). (52425203)