新型炭材料（中英文）2025，Vol.40Issue(3)：477-518,42.DOI:10.1016/S1872-5805(25)60989-9
3D石墨烯材料的先进能量转换与存储应用进展
A review of 3D graphene materials for energy storage and conversion
摘要
Abstract
Three-dimensional(3D)graphene monoliths are a new carbon material,that has tremendous potential in the fields of energy conversion and storage.They can solve the limitations of two-dimensional(2D)graphene sheets,including interlayer restack-ing,high contact resistance,and insufficient pore accessibility.By constructing intercon-nected porous networks,3D graphenes not only retain the intrinsic advantages of 2D graphene sheets,such as high specific surface area,excellent electrical and thermal conductivities,good mechanical properties,and outstanding chemical stability,but also enable efficient mass transport of external fluid species.We summarize the fabrica-tion methods for 3D graphenes,with a particular focus on their applications in energy-related systems.Techniques including chemical reduction assembly,chemical vapor deposition,3D printing,chemical blowing,and zinc-tiered pyrolysis have been developed to change their pore structure and elemental composition,and ways in which they can be integrated with functional components.In terms of energy conversion and storage,they have found broad use in buffering mechanical impacts,suppress-ing noise,photothermal conversion,electromagnetic shielding and absorption.They have also been used in electrochemical en-ergy systems such as supercapacitors,secondary batteries,and electrocatalysis.By reviewing recent progress in structural design and new applications,we also discuss the problems these materials face,including scalable fabrication and precise pore structure control,and possible new applications.关键词
石墨烯/3D网络/合成/能量存储/能量转换Key words
Graphene/3D network/Synthesis/Energy storage/Energy conversion分类
化学化工引用本文复制引用
吴梓源,徐炽炜,曾晋珏,蒋湘芬,王学斌..3D石墨烯材料的先进能量转换与存储应用进展[J].新型炭材料（中英文）,2025,40(3):477-518,42.基金项目
This work is supported by National Natural Sci-ence Foundation of China(52272039,U23B2075,51972168),Key Research and Development Program in Jiangsu Province(BE2023085),Natural Science Foundation of Jiangsu Province of China(BK20231406),and Center for Microscopy and Ana-lysis of Nanjing University of Aeronautics and Astro-nautics. 国家自然科学基金(52272039,U23B2075,51972168) （52272039,U23B2075,51972168）
江苏省重点研发计划(BE2023085) （BE2023085）
江苏省自然科学基金(BK20231406). （BK20231406）
