新型炭材料（中英文）2025，Vol.40Issue(3)：519-539,21.DOI:10.1016/S1872-5805(25)60992-9
石墨烯组装膜作为电化学反应平台的研究进展
A review of graphene assembled films as platforms for electrochemical reactions
摘要
Abstract
Because of their low electrical conductivity,sluggish ion diffu-sion,and poor stability,conventional electrode materials are not able to meet the growing demands of energy storage and portable devices.Graphene as-sembled films(GAFs)formed from graphene nanosheets have an ultrahigh conductivity,a unique 2D network structure,and exceptional mechanical strength,which give them the potential to solve these problems.However,a systematic understanding of GAFs as an advanced electrode material is lack-ing.This review focuses on the use of GAFs in electrochemistry,providing a comprehensive analysis of their synthesis methods,surface/structural charac-teristics,and physical properties,and thus understand their structure-prop-erty relationships.Their advantages in batteries,supercapacitors,and electro-chemical sensors are systematically evaluated,with an emphasis on their ex-cellent electrical conductivity,ion transport kinetics,and interfacial stability.The existing problems in these devices,such as chemical inertness and mechanical brittleness,are discussed and potential solutions are proposed,including defect engineering and hybrid structures.This review should deepen our mechanistic understanding of the use of GAFs in electrochemical systems and provide action-able strategies for developing stable,high-performance electrode materials.关键词
石墨烯组装膜/电池/超级电容器/电化学传感器/合成方法Key words
Graphene assembled films/Batteries/Supercapacitors/Electrochemical sensors/Synthesis methods分类
化学化工引用本文复制引用
朱永芳,吉晓东,潘文凯,吴耕,李鹏,刘波,何大平..石墨烯组装膜作为电化学反应平台的研究进展[J].新型炭材料（中英文）,2025,40(3):519-539,21.基金项目
The authors sincerely acknowledge financial sup-port from the National Natural Science Foundation of China(22279097),the Key R&D Program of Hubei Province(2023BAB103),the PhD Scientific Re-search and Innovation Foundation of The Education Department of Hainan Province Joint Project of San-ya Yazhou Bay Science and Technology City(HSPHDSRF-2024-03-022). 国家自然科学基金面上项目(22279097) （22279097）
湖北省重点研发计划(技术创新类项目,2023BAB103) （技术创新类项目,2023BAB103）
海南省教育厅三亚崖州湾科技城博士研究生科研创新基金联合项目(HSPHDSRF-2024-03-022). （HSPHDSRF-2024-03-022）
