电化学(中英文)2025,Vol.31Issue(4):32-43,12.DOI:10.61558/2993-074X.3540
单元化再生燃料电池中膜电极组件催化剂层的变化
Variation of Membrane Electrode Assembly Catalyst Layer in Unitized Regenerative Fuel Cell
摘要
Abstract
A unitized regenerative fuel cell(URFC)is a device that may function reversibly as either a fuel cell(FC)or water elec-trolysis(WE).An important component of this device is the Membrane electrode assembly(MEA).Therefore,this study aimed to compare the performance outcomes of MEA using electrodes with single and three catalyst layers.This study measured Electrochemical Surface Area(ECSA),Electrochemical Impedance Spectroscopy(EIS),X-ray Diffraction analysis(XRD),and X-ray Fluorescence(XRF).Furthermore,the round-trip efficiency(RTE)of the MEA,as well as the performance in FC and WE mode,was measured.In comparison,The ECSA values of Pt-Ru/C and Pt/C with three catalyst layers were higher than the single catalyst layer.This result was supported by electrode characterization data for XRD and XRF.The respective electrical conductivity values of Pt-Ru/C and Pt/C with three catalyst layers are also higher than the single cata-lyst layer,and the performance of URFC using MEA with three catalyst layers has the highest value of RTE among the MEA performances of URFC,which is 100%at a current density of 4 mA·cm-2.关键词
单元化再生燃料电池/往返效率/铂钌合金/碳/膜电极组件/电化学表面积Key words
Unitized regenerative fuel cell/Round trip efficiency/Pt-Ru/C/Membrane electrode assembly/Electrochemical surface area引用本文复制引用
努尔乔利法·尤兰达,罗亨迪·德迪,马吉兰·赫里安托·埃迪,萨里夫·尼尔万,拉赫马特·阿迪,尤利安蒂·哈瓦·德威,S·费布里卡·尼玛斯..单元化再生燃料电池中膜电极组件催化剂层的变化[J].电化学(中英文),2025,31(4):32-43,12.基金项目
The authors would like to acknowledge the Cen-ter of Research Excellent in Fuel Cell and Hydrogen,Universitas Sriwijaya,Palembang,South Suma-tra,Indonesia,for providing the facilities to do the research work and the financial support from the Ministry of Higher Education Malaysia under grant HICOE-2023-005. ()