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单元化再生燃料电池中膜电极组件催化剂层的变化

努尔乔利法·尤兰达 罗亨迪·德迪 马吉兰·赫里安托·埃迪 萨里夫·尼尔万 拉赫马特·阿迪 尤利安蒂·哈瓦·德威 S·费布里卡·尼玛斯

电化学(中英文)2025,Vol.31Issue(4):32-43,12.
电化学(中英文)2025,Vol.31Issue(4):32-43,12.DOI:10.61558/2993-074X.3540

单元化再生燃料电池中膜电极组件催化剂层的变化

Variation of Membrane Electrode Assembly Catalyst Layer in Unitized Regenerative Fuel Cell

努尔乔利法·尤兰达 1罗亨迪·德迪 2马吉兰·赫里安托·埃迪 3萨里夫·尼尔万 2拉赫马特·阿迪 2尤利安蒂·哈瓦·德威 4S·费布里卡·尼玛斯4

作者信息

  • 1. 化学系硕士项目,数学与自然科学学院,斯里维贾亚大学,印尼,30121
  • 2. 化学系,数学与自然科学学院,斯里维贾亚大学,印尼,30862||燃料电池与氢能研究中心,斯里维贾亚大学,印尼,30128
  • 3. 燃料电池研究所,马来西亚国民大学,雪兰莪,马来西亚,43600
  • 4. 化学项目,计算机与科学学院,印度尼西亚-印度全球曼迪里大学,印尼,30129||燃料电池与氢能研究中心,斯里维贾亚大学,印尼,30128
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摘要

Abstract

A unitized regenerative fuel cell(URFC)is a device that may function reversibly as either a fuel cell(FC)or water elec-trolysis(WE).An important component of this device is the Membrane electrode assembly(MEA).Therefore,this study aimed to compare the performance outcomes of MEA using electrodes with single and three catalyst layers.This study measured Electrochemical Surface Area(ECSA),Electrochemical Impedance Spectroscopy(EIS),X-ray Diffraction analysis(XRD),and X-ray Fluorescence(XRF).Furthermore,the round-trip efficiency(RTE)of the MEA,as well as the performance in FC and WE mode,was measured.In comparison,The ECSA values of Pt-Ru/C and Pt/C with three catalyst layers were higher than the single catalyst layer.This result was supported by electrode characterization data for XRD and XRF.The respective electrical conductivity values of Pt-Ru/C and Pt/C with three catalyst layers are also higher than the single cata-lyst layer,and the performance of URFC using MEA with three catalyst layers has the highest value of RTE among the MEA performances of URFC,which is 100%at a current density of 4 mA·cm-2.

关键词

单元化再生燃料电池/往返效率/铂钌合金/碳/膜电极组件/电化学表面积

Key words

Unitized regenerative fuel cell/Round trip efficiency/Pt-Ru/C/Membrane electrode assembly/Electrochemical surface area

引用本文复制引用

努尔乔利法·尤兰达,罗亨迪·德迪,马吉兰·赫里安托·埃迪,萨里夫·尼尔万,拉赫马特·阿迪,尤利安蒂·哈瓦·德威,S·费布里卡·尼玛斯..单元化再生燃料电池中膜电极组件催化剂层的变化[J].电化学(中英文),2025,31(4):32-43,12.

基金项目

The authors would like to acknowledge the Cen-ter of Research Excellent in Fuel Cell and Hydrogen,Universitas Sriwijaya,Palembang,South Suma-tra,Indonesia,for providing the facilities to do the research work and the financial support from the Ministry of Higher Education Malaysia under grant HICOE-2023-005. ()

电化学(中英文)

OA北大核心

1006-3471

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