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静态与动态过程中松树皮、核桃壳吸附典型污染物的特性

邱霖 刘勇 江成 聂发辉 曹文平

能源研究与管理2025,Vol.17Issue(2):79-89,11.
能源研究与管理2025,Vol.17Issue(2):79-89,11.DOI:10.16056/j.2096-7705.2025.02.009

静态与动态过程中松树皮、核桃壳吸附典型污染物的特性

Characteristics of Typical Pollutants Adsorbed by Pine Bark and Walnut Shell in Static and Dynamic Processes

邱霖 1刘勇 2江成 2聂发辉 3曹文平4

作者信息

  • 1. 江西省科学院能源研究所,温室气体核算与碳减排江西省重点实验室,南昌 330096||华东交通大学土木建筑学院,南昌 330013
  • 2. 江西省科学院能源研究所,温室气体核算与碳减排江西省重点实验室,南昌 330096||江西省碳中和研究中心,南昌 330096
  • 3. 华东交通大学土木建筑学院,南昌 330013
  • 4. 江苏莲洋港环保科技有限公司,江苏徐州 221003
  • 折叠

摘要

Abstract

To assess the efficacy of agricultural and forestry wastes as adsorbents,this study employed pine bark and walnut shell as subjects,characterizing them using scanning electron microscopy,X-ray diffraction,and other analytical techniques to elucidate their adsorption mechanisms.Static and dynamic tests were conducted to analyze their actual adsorption capacities.The findings indicate that,pine bark and walnut shell are representative biomass materials,with phase compositions compri-sing organic macromolecules such as cellulose,hemicellulose,and lignin.However,their surface structures differ signifi-cantly.Both materials exhibit a rich presence of oxygen-containing functional groups,showing high similarity in this aspect.During static tests,pine bark and walnut shell demonstrated considerable adsorption potential.In dynamic vertical flow experiments,their adsorption performance for various pollutants varied notably,with an average removal rate for TP of only 20%~30%.This disparity is attributed to the selective adsorption properties of the surface oxygen-containing functional groups,which tend to adsorb different types of pollutants preferentially.The adsorption effects on NH4+-N and COD were more pronounced than on TP,largely due to mechanisms such as precipitation reactions and ion exchange.Consequently,pine bark and walnut shell exhibit a strong adsorption effect on typical pollutants and,given their wide availability,are excellent adsorbent materials.

关键词

农林废弃物/动态垂直流/吸附特性/溶解性有机质/机理

Key words

agricultural and forestry wastes/dynamic vertical flow/adsorption characteristics/dissolved organic matter/mechanism

分类

环境科学

引用本文复制引用

邱霖,刘勇,江成,聂发辉,曹文平..静态与动态过程中松树皮、核桃壳吸附典型污染物的特性[J].能源研究与管理,2025,17(2):79-89,11.

基金项目

江西省自然基金项目(20242BAB25323) (20242BAB25323)

江苏省333高层次人才项目 ()

江西省科学院基础研究项目(2023YJC2009) (2023YJC2009)

江西省科学院包干制试点示范项目(2023YSBG2201) (2023YSBG2201)

能源研究与管理

2096-7705

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