林产化学与工业2025，Vol.45Issue(3)：107-112,6.DOI:10.20195/j.issn.0253-2417.2024043
氧化纤维素增强全生物基大豆蛋白膜的制备
Study on the Preparation of Full Bio-based Soy Protein Film Reinforced by Oxidized Cellulose
摘要
Abstract
A series of full bio-based soybean protein films(SPFO-X)were prepared by utilizing the self-assembly effect of soybean protein and the Schiff base reaction between oxidized cellulose(OMCC)and the amino groups of soybean protein.The structural changes of soybean protein were investigated using transmission electron microscopy(TEM)and circular dichroism(CD)spectroscopy.The structure and properties of the fully bio-based soybean protein film materials were characterized by scanning electron microscopy(SEM),fourier transform infrared spectroscopy(FT-IR),X-ray photoelectron spectroscopy(XPS),and other techniques.The experimental results demonstrated that the spatial structure of soybean protein was disrupted during the ultrasonic treatment,leading to the self-assembly of highly crystalline fibrillar structures.This fibrillar structure significantly enhanced the mechanical properties of the film,increasing the tensile strength from 8.7 MPa(unfibrotic soy protein film)to 27.8 MPa.With the addition of OMCC,the aldehyde and amino groups underwent a Schiff base reaction,which further improved the tensile strength of the soybean protein-based film.When 10％OMCC was added,the tensile strength of the resulting film,SPFO-10,increased to 66.1 MPa.Solvent resistance and recovery tests revealed that the fully bio-based soybean protein films could withstand corrosion by various common solvents and be effectively degraded using specific solvents.关键词
全生物基/自组装/希夫碱反应/耐溶剂Key words
all-biomass-based/self-assembly/Schiff base reaction/solvent resistance分类
化学化工引用本文复制引用
叶韧,王楚楚,陈秀兰,储富祥,王春鹏..氧化纤维素增强全生物基大豆蛋白膜的制备[J].林产化学与工业,2025,45(3):107-112,6.基金项目
国家重点研发计划资助项目(2022YFD2200701) （2022YFD2200701）
