南京工业大学学报（自然科学版）2025，Vol.47Issue(3)：237-243,7.DOI:10.3969/j.issn.1671-7627.2025.03.002
改性纳米MgO氟碳脱酸液的制备及其纸张脱酸性能
Preparation and deacidification performance for paper of modified nanometer MgO fluorocarbon deacidification solution
摘要
Abstract
Nanometer MgO was synthesized via anodic oxidation electrolysis and modified with polyvinylpyrrolidone(PVP),cetyltrimethylammonium bromide(CTAB),and sodium dodecylbenzenesulfonate(SDBS).The dispersion and stability of nanometer MgO in methyl perfluoroisobutyl ether fluorocarbon solvent were investigated.The nanometer MgO fluorocarbon solvent was used as a deacidification solution for the Qing Dynasty paper.The effects of nanometer MgO fluorocarbon deacidification solution containing different surfactants on paper deacidification performance were studied.The results showed that nanometer MgO modified with 2％CTAB exhibited the best dispersion in the fluorocarbon solvent and achieved the best deacidification effect,remaining suspended for 60 minutes.After treatment with the deacidification solution,the pH of the paper increased to 7.51,and the alkaline reserve was 0.51 mol/kg.The whiteness of the paper remained almost unchanged,with a slight reduction in color difference.The tensile strength increased by 64.5％,showing that the solution provided excellent protection for the paper and could extend its shelf life.关键词
纳米氧化镁/表面活性剂/表面改性/氟碳溶剂/文物保护/纸张脱酸/脱酸液Key words
nanometer MgO/surfactants/surface modification/fluorocarbon solvent/cultural heritage preservation/paper deacidification/deacidification solution分类
化学引用本文复制引用
姚敏,朱承飞,刘文娟,桂明,陈德龙..改性纳米MgO氟碳脱酸液的制备及其纸张脱酸性能[J].南京工业大学学报（自然科学版）,2025,47(3):237-243,7.基金项目
国家重点研发计划(2022YFF0904202) （2022YFF0904202）
