日用化学工业（中英文）2025，Vol.55Issue(6)：700-708,9.DOI:10.3969/j.issn.2097-2806.2025.06.003
颗粒型聚醚:一类新型的非水基泡沫消泡剂
Particulated polyether:A novel defoamer for nonaqueous foams
摘要
Abstract
Using triblock copolymer poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)and citric acid as raw materials,a novel polyether was synthesized through condensation-carbonization under high temperature,which had a hyperbranched structure using nanocarbon as the core,or crosslinked morphology connected by nanocarbon.The mixture of triethanolamine monooleate/p-xylene was selected as a model system to produce nonaqueous foam.It was found that the synthesized polyether had a high defoaming efficiency up to 86%within 30 min,demonstrating a defoaming rate over 2 000 times that of the defoamer-free system.Furthermore,the crude oil from Gudao oil production plant was foamed under high pressure of CO2.The polyether also showed good defoaming efficiency to this foam of crude oil.Our work might provide a new strategy to synthesize nanocarbon-hybridized polyether,which could find applications in cases where defoamers based on organosilicone could hardly be used on a large scale,e.g.,the foamed oil produced by the oilfield auxiliary chemicals that are intensively used during oil exploitation.关键词
颗粒型/聚醚/非水基/泡沫/消泡剂Key words
particulate/polyether/nonaqueous/foam/defoamer分类
化学工程引用本文复制引用
王玉江,汤龙皓,刘晓倩,冯宁,李洪光..颗粒型聚醚:一类新型的非水基泡沫消泡剂[J].日用化学工业（中英文）,2025,55(6):700-708,9.基金项目
国家自然科学基金面上项目(21875129) （21875129）
