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超级电容器用酚醛树脂/竹基复合活性炭的制备及表征

文秀婵 张博 王玺 桂柳成 黄思玉 何旻雁

广西师范大学学报(自然科学版)2025,Vol.43Issue(4):147-156,10.
广西师范大学学报(自然科学版)2025,Vol.43Issue(4):147-156,10.DOI:10.16088/j.issn.1001-6600.2024041702

超级电容器用酚醛树脂/竹基复合活性炭的制备及表征

Preparation and Characterization of Phenolic Resin/Bamboo Based Composite Activated Carbon for Supercapacitors

文秀婵 1张博 1王玺 1桂柳成 2黄思玉 3何旻雁3

作者信息

  • 1. 广西师范大学 环境与资源学院,广西 桂林 541006
  • 2. 广西师范大学 化学与药学学院,广西 桂林 541004
  • 3. 广西师范大学 环境与资源学院,广西 桂林 541006||珍稀濒危动植物生态与环境保护教育部重点实验室(广西师范大学),广西 桂林 541006
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摘要

Abstract

To investigate the effect of phenolic resin addition on the microstructure and electrochemical properties of carbon materials,and to obtain a relatively economical method of preparing carbon materials for supercapacitors,phenolic resin/bamboo based composite activated carbon was prepared by KOH activation using bamboo waste as raw material and phenolic resin as modifier.The results showed that the microstructure of the composite activated carbon was affected by the addition of phenolic resin.The specific surface area and total pore volume of the composite activated carbon with the resin addition of 15%~35%increased.The average pore diameter decreased,providing more adsorption sites for storage charge.The specific surface area and total pore volume of the composite activated carbon were increased by 28.5%and 29.2%,respectively,and the average pore size was reduced to 1.78 nm compared with that of the bamboo-based activated carbon when 35%of phenolic resin was added;the specific capacitance at a current density of 0.5 A·g-1 reached 263.85 F·g-1,which was 53.3%higher than bamboo activated carbon.The results indicated that the electrochemical properties of activated carbon prepared by adding phenolic resin were obviously improved.

关键词

复合活性炭/酚醛树脂/竹基/可调控/微观结构/超级电容器/电化学性能

Key words

composite activated carbon/phenolic resin/bamboo-based/adjustable/microstructure/supercapacitor/electrochemical performance

分类

化学化工

引用本文复制引用

文秀婵,张博,王玺,桂柳成,黄思玉,何旻雁..超级电容器用酚醛树脂/竹基复合活性炭的制备及表征[J].广西师范大学学报(自然科学版),2025,43(4):147-156,10.

基金项目

国家自然科学基金(22165003) (22165003)

广西师范大学学报(自然科学版)

OA北大核心

1001-6600

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