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桐油-海藻酸钙自修复涂层的制备及性能研究

王娟 马凤仓 刘平 张柯 陈小红

有色金属材料与工程2025,Vol.46Issue(3):19-25,7.
有色金属材料与工程2025,Vol.46Issue(3):19-25,7.DOI:10.13258/j.cnki.nmme.20230410002

桐油-海藻酸钙自修复涂层的制备及性能研究

Preparation and properties of tung oil-calcium alginate self-healing coating

王娟 1马凤仓 1刘平 1张柯 1陈小红1

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093
  • 折叠

摘要

Abstract

Stainless steel is widely used in implant materials and medical devices,but it is susceptible to corrosion in the human body environment,which can lead to device failure.To address this problem,a self-healing coating was designed.Core-shell microcapsules of tung oil-calcium alginate with medical tung oil as the core and calcium alginate as the shell material were prepared by in situ emulsion polymerization,and then the microcapsules were dispersed in modified silicone gel to form a wear-resistant and corrosion-resistant coating.The microcapsules were characterized by scanning electron microscope,Fourier transform infrared spectrometer and thermogravimetric analyzer.The results show that when the mass fraction of microcapsule in the coating is 15%,the wear resistance is optimal,the friction coefficient is as low as 0.32,and the wear depth is only 0.35 mm.After being immersed in the simulated body fluid for 20 d,the low-frequency impedance was 7.0×105 Ω·cm2,which demonstrated that tung oil as the core has a self-healing effect on microcracks.

关键词

海藻酸钙/桐油/耐摩擦磨损性能/耐腐蚀性能

Key words

calcium alginate/tung oil/friction and wear resistance performance/corrosion resistance

分类

矿业与冶金

引用本文复制引用

王娟,马凤仓,刘平,张柯,陈小红..桐油-海藻酸钙自修复涂层的制备及性能研究[J].有色金属材料与工程,2025,46(3):19-25,7.

基金项目

国家自然科学基金资助项目(51771119) (51771119)

有色金属材料与工程

2096-2983

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