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nZVI负载MCS阴极用于固定化MFC-EF系统的效能研究

张栋年 胡志宏 朱浩 由长宇 曲毅 王景祺 王斐 仲崇方 李怀珠 林世坤 赵虎

陕西科技大学学报2025,Vol.43Issue(4):39-48,74,11.
陕西科技大学学报2025,Vol.43Issue(4):39-48,74,11.

nZVI负载MCS阴极用于固定化MFC-EF系统的效能研究

Study on the efficacy of nZVI loaded MCS cathode used in immobilized MFC-EF system

张栋年 1胡志宏 2朱浩 1由长宇 1曲毅 3王景祺 1王斐 4仲崇方 1李怀珠 2林世坤 2赵虎2

作者信息

  • 1. 兰州大学 资源环境学院,甘肃兰州 730000
  • 2. 甘肃省高速公路服务集团有限公司,甘肃兰州 730030
  • 3. 毅康科技有限公司,山东烟台 264006
  • 4. 长江生态环保集团有限公司,湖北武汉 430014
  • 折叠

摘要

Abstract

A novel catalyst was prepared through calcination,liquid-phase reduction,and vacu-um freeze-drying techniques,consisting of nanoscale zero-valent iron(nZVI)supported on melamine-based carbon foam(MCS)for application in cathodic Fenton reactions.The cata-lyst also served as an anode microbial immobilization material to enhance electron transfer ef-ficiency and degradation efficiency,thereby constructing an integrated microbial fuel cell and electro-Fenton technology wastewater treatment system(IMFC-EF).The electrochemical performance and pollutant degradation effects of the IMFC-EF coupling system were investi-gated using simulated domestic sewage and industrial wastewater.Results indicated that nZ-VI was successfully loaded onto MCS,and the resulting cathode catalyst exhibited excellent characteristics such as a large specific surface area,high porosity,and easy recyclability,which improved the degradation efficiency of Rhodamine B(RhB)at the cathode(90.29%).Immobilized microorganisms effectively enhanced the microbial activity and power generation efficiency at the anode,increasing the maximum power density of the coupled system(4.86 W/m3)and improving the removal effect of anodic COD(84%).This work achieved the sim-ultaneous treatment of simulated domestic sewage and RhB,providing a new approach for the treatment of actual wastewater.

关键词

微生物燃料电池/固定化/纳米零价铁/三聚氰胺衍生碳泡沫/电芬顿/罗丹明B

Key words

microbial fuel cell/immobilization/nanosized zero-valent iron/melamine derived carbon foam/electro-fenton/Rhodamine B

分类

资源环境

引用本文复制引用

张栋年,胡志宏,朱浩,由长宇,曲毅,王景祺,王斐,仲崇方,李怀珠,林世坤,赵虎..nZVI负载MCS阴极用于固定化MFC-EF系统的效能研究[J].陕西科技大学学报,2025,43(4):39-48,74,11.

基金项目

甘肃省交通运输厅科技项目(KY-2020-001) (KY-2020-001)

兰州大学-毅康科技有限公司节能环保先进技术产业研究院科技项目((21)0953) ((21)

陕西科技大学学报

OA北大核心

2096-398X

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