陕西科技大学学报2025,Vol.43Issue(4):39-48,74,11.
nZVI负载MCS阴极用于固定化MFC-EF系统的效能研究
Study on the efficacy of nZVI loaded MCS cathode used in immobilized MFC-EF system
摘要
Abstract
A novel catalyst was prepared through calcination,liquid-phase reduction,and vacu-um freeze-drying techniques,consisting of nanoscale zero-valent iron(nZVI)supported on melamine-based carbon foam(MCS)for application in cathodic Fenton reactions.The cata-lyst also served as an anode microbial immobilization material to enhance electron transfer ef-ficiency and degradation efficiency,thereby constructing an integrated microbial fuel cell and electro-Fenton technology wastewater treatment system(IMFC-EF).The electrochemical performance and pollutant degradation effects of the IMFC-EF coupling system were investi-gated using simulated domestic sewage and industrial wastewater.Results indicated that nZ-VI was successfully loaded onto MCS,and the resulting cathode catalyst exhibited excellent characteristics such as a large specific surface area,high porosity,and easy recyclability,which improved the degradation efficiency of Rhodamine B(RhB)at the cathode(90.29%).Immobilized microorganisms effectively enhanced the microbial activity and power generation efficiency at the anode,increasing the maximum power density of the coupled system(4.86 W/m3)and improving the removal effect of anodic COD(84%).This work achieved the sim-ultaneous treatment of simulated domestic sewage and RhB,providing a new approach for the treatment of actual wastewater.关键词
微生物燃料电池/固定化/纳米零价铁/三聚氰胺衍生碳泡沫/电芬顿/罗丹明BKey words
microbial fuel cell/immobilization/nanosized zero-valent iron/melamine derived carbon foam/electro-fenton/Rhodamine B分类
资源环境引用本文复制引用
张栋年,胡志宏,朱浩,由长宇,曲毅,王景祺,王斐,仲崇方,李怀珠,林世坤,赵虎..nZVI负载MCS阴极用于固定化MFC-EF系统的效能研究[J].陕西科技大学学报,2025,43(4):39-48,74,11.基金项目
甘肃省交通运输厅科技项目(KY-2020-001) (KY-2020-001)
兰州大学-毅康科技有限公司节能环保先进技术产业研究院科技项目((21)0953) ((21)