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可生物降解锂基润滑脂的制备及其性能

杨珊珊 张利 来冰冰 王晓波 刘宗柱 娄文静

材料科学与工程学报2025,Vol.43Issue(3):405-414,10.
材料科学与工程学报2025,Vol.43Issue(3):405-414,10.DOI:10.14136/j.cnki.issn1673-2812.2025.03.009

可生物降解锂基润滑脂的制备及其性能

Preparation and Properties of Biodegradable Lithium Grease

杨珊珊 1张利 2来冰冰 3王晓波 3刘宗柱 4娄文静3

作者信息

  • 1. 中国科学院兰州化学物理研究所,润滑材料全国重点实验室,甘肃兰州 730000||青岛农业大学生命科学学院,山东,青岛 266109
  • 2. 青岛中科润美润滑材料科技有限公司,山东青岛 266100
  • 3. 中国科学院兰州化学物理研究所,润滑材料全国重点实验室,甘肃兰州 730000||青岛市资源化学与新材料研究中心,青岛市高端装备润滑技术重点实验室,山东青岛 266100
  • 4. 青岛农业大学生命科学学院,山东,青岛 266109
  • 折叠

摘要

Abstract

Using soybean oil,rapeseed oil,and castor oil as raw materials and common mineral oil 150N as control,lithium grease was prepared by pre-soap method with the same soap content,and the effects of the physical and chemical properties,rheological properties,biodegradability and tribological properties of the prepared grease were studied.The results showed that the viscosity of the base oil was correlated with the rheological and tribological properties of the grease.The thinner the consistency of the grease and the higher the viscosity of the base oil,the lower the structural strength of the grease,the better the thixotropy performance,and the better the antifriction performance.Through biodegradation experiments,it was found that vegetable oil lithium grease was better than mineral oil lithium grease,and the biodegradation rate of castor oil lithium-based grease was the best,up to 79.69%.According to the XPS analysis of the wear surface,the castor oil lithium base grease works together through the physical adsorption film and the subsequent chemical reaction film during the friction process,to achieve the anti-friction effect.Among the three biodegradable lithium greases,castor oil lithium-based grease colloid has poor stability,but it has excellent thixotropy,biodegradability,and tribological properties.

关键词

植物油/锂基润滑脂/流变性能/摩擦学性能/生物降解性能

Key words

Vegetable oil/Lithium grease/Rheological properties/Tribological properties/Biodeg-radability

分类

化学化工

引用本文复制引用

杨珊珊,张利,来冰冰,王晓波,刘宗柱,娄文静..可生物降解锂基润滑脂的制备及其性能[J].材料科学与工程学报,2025,43(3):405-414,10.

基金项目

山东省泰山学者青年专家计划项目(2022CXGC020309)和山东省重点研发计划项目(2020CXGC011002) (2022CXGC020309)

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