纺织高校基础科学学报2025,Vol.38Issue(3):14-22,9.DOI:10.13338/j.issn.1006-8341.2025.03.002
纤维基AgNPs@ZIF-8异质结材料的制备及其光催化性能
Preparation and photocatalytic performance of fiber-based AgNPs@ZIF-8 heterostructure materials
摘要
Abstract
Photocatalysts constructed from metal-organic framework,such as ZIF-8 remain hampered by significant limitations,including suboptimal catalytic efficiency and insufficient stability.AgNPs@ZIF-8 heterojunction nanomaterials were synthesized and subsequently immobilized on PVDF nanofibers using screen-printing techniques to fabricate an efficient and stable nanofiber-based pho-tocatalyst.The structural properties of the material were comprehensively characterized by using X-ray diffraction(XRD),fourier-transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),and UV-Vis-NIR spectroscopy.And the degradation performence of the mate-rial for methylene blue was tested by photocatalytic experiment.The results demonstrated that AgNPs@ZIF-8 exhibited markedly enhanced photoelectrochemical properties compared to pure ZIF-8.Under a water flow rate of 500 mL/min,photocatalytic reaction rate constant of the AgNPs@ZIF-8/PVDF composite nanofiber membrane the was 2.6 times higher than that of the nanoparticles,with an MB degradation efficiency reaching 70%and exhibiting excellent stability.This study provides a foundational platform for the practical implementation of flow-driven photocatalysis in industrial wastewater treatment.关键词
金属有机框架/纤维/复合材料/光催化/静电纺丝Key words
metal-organic frameworks/fiber/composites/photocatalysis/electro-spinning分类
化学化工引用本文复制引用
刘桂连,成佳哲,贾浩..纤维基AgNPs@ZIF-8异质结材料的制备及其光催化性能[J].纺织高校基础科学学报,2025,38(3):14-22,9.基金项目
江苏省自然科学基金(BK20210480) (BK20210480)