首页|期刊导航|纺织高校基础科学学报|木棉纤维对羧甲基壳聚糖海绵的结构与性能影响

木棉纤维对羧甲基壳聚糖海绵的结构与性能影响OA

Effects of kapok fiber on the structure and properties of carboxymethyl chitosan sponge

中文摘要英文摘要

为了探究木棉纤维填充对羧甲基壳聚糖海绵(CMVA)多孔结构、力学性能及吸水性能的调控机制,制备了不同纤维含量的羧甲基壳聚糖海绵.采用傅里叶变换红外光谱(FT-IR)分析化学相互作用,结合扫描电子显微镜(SEM)表征微观结构,通过压缩实验和吸水率测试评价力学性能及吸液行为.结果显示,木棉纤维可能与羧甲基壳聚糖发生酯交换反应;中空木棉纤维的加入将海绵的孔隙连通,形成复杂多孔结构;纤维的加入能有效承担载荷,含有质量分数为0.3%的木棉纤维的海绵显著提升了海绵的压缩强度,减少了塑性形变区域,并增强了其形状恢复能力和吸水性能.该研究创新性地利用纤维-海绵增强手段,为开发高性能羧甲基壳聚糖海绵提供了重要理论依据,具有广阔的应用前景.

To investigate the modulation mechanism of kapok fiber filling on the porous structure,mechanical properties and water absorption properties of carboxymethyl chitosan sponge(CMVA),carboxymethyl chitosan sponges with different fiber contents were prepared.The chemical inter-actions were analyzed by Fourier transform infrared spectroscopy(FT-IR),SEM was used to char-acterize the microstructure,and the mechanical properties and water absorption behaviors were evaluated by compression test and water absorption test.The results show that the kapok fibers might undergo esterification reaction with carboxymethyl chitosan.The incorporation of hollow wood wool fibers connects the pores of the sponge to form a complex porous structure.The in-corporation of fibers is effective in bearing loads,and the sponges with 0.3%mass fraction of ka-pok fibers significantly increase the compressive strength of the sponge,reduce the plastic deforma-tion region,and enhance its shape recovery and water absorption properties.The innovative use of fiber-sponge reinforcement in this study provides an important theoretical basis for the devel-opment of high-performance carboxymethyl chitosan sponges,which have a broad application pro-spect.

王世新;蔡昊鑫;齐伊明;林恒;邓红兵

东华大学纺织学院,上海 201620||东华大学纺织科技创新中心,上海 201620东华大学纺织学院,上海 201620||东华大学纺织科技创新中心,上海 201620东华大学纺织学院,上海 201620||东华大学纺织科技创新中心,上海 201620武汉大学人民医院心内科,湖北武汉 430072东华大学纺织科技创新中心,上海 201620||武汉大学资源与环境科学学院,湖北武汉 430079

轻工纺织

木棉纤维羧甲基壳聚糖压缩回弹吸水性能

kapok fibercarboxymethyl chitosancompressive reboundwater absorption

《纺织高校基础科学学报》 2025 (3)

23-29,7

中国湖北省杰出青年学者自然科学基金(2020CFA105)

10.13338/j.issn.1006-8341.2025.03.003

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