化工进展2025，Vol.44Issue(7)：3683-3696,14.DOI:10.16085/j.issn.1000-6613.2024-0892
己二腈制备方法的研究进展
Progress research in preparation of adiponitrile
摘要
Abstract
Adiponitrile,as one of the main raw materials for producing polyamide(nylon 66),has been long monopolized by foreign companies.In recent years,the research on the high efficiency production methods of adiponitrile has gradually become a hot topic because the increasing demand of nylon 66 helped bring about the growing gap between adiponitrile supply and demand.The basic research,process characteristics and development direction of the preparation methods for adiponitrile were introduced in the article,such as butadiene method,acrylonitrile electrolytic dimerization method and adipic acid ammoniation method.In addition,the application feasibility of process intensification technology in acrylonitrile electrolytic dimerization method and adipic acid ammoniation method were discussed in depth from the view of reaction mechanism in the review.Finally,the kinetics and thermodynamics of adipic acid ammoniation were summarized.The application of the process intensification technology would be the key to promoting efficient and green production of adiponitrile,which was of great significance for the improvement and autonomy of adiponitrile production technology.关键词
己二酸氨化法/丁二烯法/丙烯腈电解二聚法/己二腈/过程强化/有机化合物/化学过程/反应动力学Key words
adipic acid ammoniation method/butadiene method/acrylonitrile electrolytic dimerization method/adiponitrile/process intensification/organic compounds/chemical processes/reaction kinetics分类
化学化工引用本文复制引用
杜磊,曹志涛,许浪,张英杰,孙宝昌,邹海魁,初广文,陈建峰..己二腈制备方法的研究进展[J].化工进展,2025,44(7):3683-3696,14.基金项目
国家自然科学基金(22288102,U22B6011). （22288102,U22B6011）
