化工学报2025，Vol.76Issue(6)：2483-2504,22.DOI:10.11949/0438-1157.20241301
烃转化过程中的氢转移反应
Hydrogen transfer reactions in hydrocarbon conversion process
摘要
Abstract
Green carbon science has become the scientific foundation for carbon neutrality.The evolution of C-C and C-H bonds during the hydrocarbon conversion process runs throughout the entire carbon cycle.In the process of C-C bond evolution,the breaking and formation of C-H bonds are inevitable,that is,hydrogen transfer reactions also exist in this process.This paper focuses on hydrogen transfer reactions in the hydrocarbon conversion process,reviewing from three dimensions:mechanisms of hydrogen transfer reactions,regulation of hydrogen transfer reactions,and application of hydrogen transfer reactions in product-oriented hydrocarbon conversion processes.From the perspective of hydrogen transfer reactions,it envisions the reasonable roles of different carbon resources(fossil resources,biomass resources,waste plastic resources,and CO2 resources)in their efficient conversion as hydrogen acceptors or hydrogen donors.Biomass and water,as potential sustainable hydrogen donors,will play a core role in the construction of future energy systems guided by green carbon science.关键词
绿色碳科学/烃转化/氢转移反应/氢受体/氢供体Key words
green carbon science/hydrocarbon conversion/hydrogen transfer reaction/hydrogen acceptors/hydrogen donors分类
化学化工引用本文复制引用
李芳,王怡然,张鹏鹤,刘月明,何鸣元..烃转化过程中的氢转移反应[J].化工学报,2025,76(6):2483-2504,22.基金项目
国家自然科学基金项目(U24B20200,22072044) （U24B20200,22072044）
