广东石油化工学院学报2025，Vol.35Issue(3)：20-24,30,6.
NiS-CoS2-Co/NC锌空气电池双功能氧电催化剂研究
NiS-CoS2-Co/NC as Bifunctional Oxygen Electrocatalyst for Rechargeable Zn-Air Batteries
摘要
Abstract
The research has successfully prepared a nitrogen-doped carbon material supported Ni and Co metal sulfides(NiS-CoS2-Co/NC)via pyrolysis of a coordination polymer of Co2+and nitrogen-containing ligands,followed by a hydrothermal reaction.The morphology,composition,and oxidation state of the prepared materials were characterized using scanning electron microscopy(SEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The electrochemical testing results showed that the prepared NiS-CoS2-Co/NC material exhibited excellent ORR/OER bifunctional electrocatalysis activity and reversibility with a charge-discharge voltage difference of 0.17 V and good rate performance.Good cycling stability can achieve for 1200 cycles with discharge voltages of 1.66 V and coulombic efficiency(CE)of above 96%.The highest CE was almost 100%.关键词
锌空气电池/正极电催化剂/过渡金属硫化物/氮掺杂碳Key words
Zn-air batteries/cathode electrocatalyst/transition metal sulfides/nitrogen-doped carbon material分类
化学化工引用本文复制引用
刘淑芝,安亚苹,李雨桐,崔宝臣,雷艳明..NiS-CoS2-Co/NC锌空气电池双功能氧电催化剂研究[J].广东石油化工学院学报,2025,35(3):20-24,30,6.基金项目
广东省自然科学基金项目(2021A1515010394) （2021A1515010394）
广东石油化工学院自然科学研究项目(人才引进)(2019rc014,2019rc022) （人才引进）
茂名绿色化工研究院科技项目(MMGCIRI-2022YFJH-Y-004). （MMGCIRI-2022YFJH-Y-004）
