物理化学学报2025，Vol.41Issue(7)：44-64,21.DOI:10.1016/j.actphy.2025.100073
非均相催化CO2与烃类协同催化转化的最新进展
Recent advances in synergistic catalytic valorization of CO2 and hydrocarbons by heterogeneous catalysis
摘要
Abstract
The escalating frequency of extreme weather events globally has necessitated immediate action to mitigate the impacts and threats posed by excessive greenhouse gas emissions,particularly carbon dioxide(CO2).Consequently,reducing CO2 emissions has become imperative,with decarbonization techniques being extensively investigated worldwide to achieve net-zero emissions.From an energy perspective,CO2 represents an abundant and low-cost carbon resource that can be converted into high-value chemical products through reactions with hydrocarbons,including alkanes,alkenes,aromatic hydrocarbons,and polyolefins.Through hydrogen transfer,CO2 can be reduced to CO,accompanied by the formation of H2O.CO2 and hydrocarbons can also be transformed into syngas(CO and H2)via dry reforming.Furthermore,CO2 can be incorporated into hydrocarbon molecules,resulting in carbon chain growth,such as the production of alcohols,carboxylic acids,and aromatics.However,due to the thermodynamic stability and kinetic inertness of CO2,as well as the high bond energy and low polarity of hydrocarbon C―H bonds,the conversion of CO2 and hydrocarbons remains a highly challenging and demanding strategic objective.This review focuses on the synergistic catalytic valorization of CO2 and hydrocarbons using heterogeneous catalysts,summarizing recent advancements in coupling CO2 with various hydrocarbons.It also examines relevant kinetic models,including Langmuir-Hinshelwood and Eley-Rideal mechanisms.For catalyst design,bifunctional catalysts with distinct active sites can independently activate these two reactive molecules,and the modulation of acid-base properties,oxygen vacancies,and interfacial interactions represents an effective strategy to optimize catalytic performance.Finally,future directions for advancing CO2-hydrocarbon co-utilization technologies are proposed,along with recommendations for low-carbon development strategies.关键词
二氧化碳/烃类/协同催化增值/增值化学品/非均相催化Key words
CO2/Hydrocarbons/Synergistic catalytic valorization/Value-added chemicals/Heterogeneous catalysis分类
化学化工引用本文复制引用
张红红,魏振,Derek Hao,敬林,刘雨溪,戴洪兴,魏伟钦,邓积光..非均相催化CO2与烃类协同催化转化的最新进展[J].物理化学学报,2025,41(7):44-64,21.基金项目
The project was supported by the National Natural Science Foundation of China(22406009,U23A20120),Natural Science Foundation of Hebei Province(B2021208033),and R&D Program of Beijing Municipal Education Commission(KZ202210005011).国家自然科学基金(22406009,U23A20120),河北省自然科学基金重点项目(B2021208033)及北京市教委科技计划重点项目(KZ202210005011)资助 （22406009,U23A20120）
