物理化学学报2025，Vol.41Issue(8)：32-57,26.DOI:10.1016/j.actphy.2025.100086
二维共价有机框架作为光催化剂在有机合成中的研究进展
Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis
摘要
Abstract
Two-dimensional covalent organic frameworks(2D COFs)exhibit distinctive characteristics,including tunable topology,an extensive specific surface area,susceptibility to functionalization,and robust stability,making them frequently utilizedin multiphase photocatalytic applications.This article begins with an overview of the synthesis methods for 2D COFs,covering solvothermal,ionothermal,mechanochemical,microwave-assisted,sonochemical,and interfacial synthesis techniques.It provides a concise introduction to various factors influencing photocatalytic performance,such as crystallinity and stability,band structure,charge transfer capability,pore size and specific surface area,and the nature of the light source.Subsequently,the discussion shifts to summarizing and analyzing advancements in the use of 2D COFs as photocatalysts for organic small molecule conversion reactions,particularly in photocatalytic oxidation,reduction,and coupling reactions.Finally,summary and outlook are presented regarding the opportunities and challenges that 2D COFs face in photocatalytic organic transformations.关键词
二维/共价有机框架/光催化/氧化反应/还原反应/偶联反应Key words
Two-dimension/Covalent organic framework/Photocatalysis/Oxidation reaction/Reduction reaction/Cross-coupling reaction分类
化学化工引用本文复制引用
袁乐汪,彭垚垚,管宗杰,方煜..二维共价有机框架作为光催化剂在有机合成中的研究进展[J].物理化学学报,2025,41(8):32-57,26.基金项目
This research was supported by National Natural Science Foundation of China(22371067).国家自然科学基金(22371067)资助 （22371067）
