物理化学学报2025，Vol.41Issue(8)：58-76,19.DOI:10.1016/j.actphy.2025.100089
电容去离子提锂技术中电极材料的研究进展
Advanced electrode materials in capacitive deionization for efficient lithium extraction
摘要
Abstract
Efficient technologies for lithium extraction are progressively pivotal in response to the growing requirement for lithium in new energy applications.However,due to its high energy consumption and possible secondary pollution problems,traditional lithium absorption and recovery technologies,are limited in practical application and development.Capacitive deionization(CDI)demonstrates significant potential for lithium extraction with regard to efficiency,cost-effectiveness,and energy consumption.This review commences with bibliometric analysis to dissect the key research topics of lithium extraction via CDI,and presents a complete synopsis of recent advances in electrode materials for lithium extraction using CDI technology,along with various types of CDI systems that utilize these materials.This study elucidates in detail the main electrode materials used in CDI systems for lithium resource recovery——aqueous lithium ion electrode materials(including LiFePO4,LiMn2O4,LiNi1/3Co1/3Mn1/3O2)and their modification materials(including carbon nanotubes,graphene,MOFs).In addition,this paper discusses the improvement of lithium extraction efficiency through different CDI systems and evaluates the capability of various advanced electrode materials in these systems.The end of the paper emphasizes the application potential of machine learning in the domain of lithium extraction via CDI.The study is anticipated to deliver a strong theoretical basis and practical recommendations for advancing efficient lithium extraction systems that utilize CDI.关键词
电容去离子/锂离子提取/电化学/电极材料Key words
Capacitive deionization/Lithium extraction/Electrochemical/Electrode material分类
化学化工引用本文复制引用
陈泽秋,蔡黎淼,关杰,李瞻洋,王昊,郭耀广,徐兴涛,潘丽坤..电容去离子提锂技术中电极材料的研究进展[J].物理化学学报,2025,41(8):58-76,19.基金项目
The project was supported by the National Natural Science Foundation of China(52400174,52270129,52370142),Shanghai Sailing Program(24YF2714000),Oriental Talent Youth Program,and Shanghai Shuguang Program(23SG52).国家自然科学基金(52400174,52270129,52370142),上海扬帆计划(24YF2714000),东方英才青年计划及上海曙光计划(23SG52)资助项目 （52400174,52270129,52370142）
