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不同酸处理工艺对石煤钒浸出特性的影响

刘明宝 李建涛 左恒 李云霄 姚国超 闫建利 马文峰 庞宏建 赵统

铀矿冶2025,Vol.44Issue(3):50-57,8.
铀矿冶2025,Vol.44Issue(3):50-57,8.DOI:10.13426/j.cnki.yky.2024.12.11

不同酸处理工艺对石煤钒浸出特性的影响

Leaching Characteristics of Stone Coal Vanadium Using Various Acid Treatment Processes

刘明宝 1李建涛 1左恒 2李云霄 2姚国超 2闫建利 3马文峰 3庞宏建 3赵统3

作者信息

  • 1. 陕西省尾矿资源综合利用重点实验室,陕西商洛 726000||商洛学院化学工程与现代材料学院,陕西商洛 726000
  • 2. 陕西五洲矿业股份有限公司,陕西商洛 726000
  • 3. 内乡县万鑫化冶有限公司,河南南阳 473000
  • 折叠

摘要

Abstract

Taking the stone coal vanadium ore in Danfeng country,Shangluo city,Shannxi province as the research object,the vanadium leaching characteristics were studied using direct acid leaching and sulphuric acid-curing leaching process,respectively.The results indicate that the optimum vanadium leaching rate is 86.7%when using direct acid leaching process under conditions of sample fineness of 45%,H2SO4 concentration of 14%,leaching period of 6 h,leaching temperature of 80 ℃,Ca(ClO)2 dosages of 3%,CaF2 dosages of 2%,and the solid-liquid ratio of 1∶2.While the vanadium leaching rate can reach to 93.5%at ambient temperature by using sulphuric acid-curing leaching process under the conditions of sample fineness of 80%,H2SO4 dosages of 20%,wetting water dosages of 7.5%,curing temperature of 110 ℃,interval time of 10 h,water leaching period of 120 min,solid-liquid ratio of 1∶2.The results for sulphuric acid-curing leaching process is better than that for direct acid leac-hing process,and the conclusion can provide technical support for vanadium extraction from stone coal in Shannan region.

关键词

石煤钒矿/酸浸/硫酸熟化/石煤/

Key words

stone coal vanadium ore/acid-leaching/sulphuric acid-curing/stone coal/vanadium

分类

矿业与冶金

引用本文复制引用

刘明宝,李建涛,左恒,李云霄,姚国超,闫建利,马文峰,庞宏建,赵统..不同酸处理工艺对石煤钒浸出特性的影响[J].铀矿冶,2025,44(3):50-57,8.

基金项目

国家自然科学基金项目(21973058) (21973058)

陕西省重点研发计划项目(2023YBSF344) (2023YBSF344)

陕西省秦创原"科学家+工程师"队伍建设项目(2024QCY-KXJ-147). (2024QCY-KXJ-147)

铀矿冶

1000-8063

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