烟台大学学报（自然科学与工程版）2025，Vol.38Issue(3)：274-281,8.DOI:10.13951/j.cnki.37-1213/n.240207
无限配位聚合物负载MXene量子点用于检测盐酸四环素
MXene Quantum Dots Modified Infinite Coordination Polymers for Tetracycline Hydrochloride Detection
摘要
Abstract
An electrochemiluminescence(ECL)sensor based on the infinite coordination polymer-supported MX-ene quantum dots(MQDs)synthesized with the rare earth element europium ion(Eu3+)and 5'-adenosine mono-phosphate(AMP)was constructed and applied to detect tetracycline hydrochloride(TH)in real water and biologi-cal samples.The results showed that with the increase of TH concentration,the ECL intensity of MQDs/Eu-AMP nanocomposite was quenched and the intensity decreased gradually.There was a good linear relationship between the ECL intensity and the concentration of TH in the range of 0.1-100 μmol·L-1.The linear equation was ΔI=74.94c+364.22(R2=0.976 6),and the lowest detection limit was 0.019 pmol·L-1(S/N=3).The quantitative detection results of TH in real samples also showed that the sensor had good detection performance.关键词
无限配位聚合物/MXene/量子点/电致化学发光/盐酸四环素Key words
infinite coordinate polymer/MXene/quantum dots/electrochemiluminescence/tetracycline hydrochlo-ride分类
化学化工引用本文复制引用
张文娟,李怡筱,田春媛,庄旭明,栾锋,邬旭然..无限配位聚合物负载MXene量子点用于检测盐酸四环素[J].烟台大学学报（自然科学与工程版）,2025,38(3):274-281,8.基金项目
山东省自然科学基金资助项目(ZR2023MB047,ZR2021MB024). （ZR2023MB047,ZR2021MB024）
