分析测试学报2025,Vol.44Issue(8):1505-1515,11.DOI:10.12452/j.fxcsxb.24123147
溶解性有机质化学组成表征方法与应用研究进展
Advances in Methods and Applications for Characterizing the Chemi-cal Composition of Dissolved Organic Matter
摘要
Abstract
Dissolved organic matter(DOM)is widely distributed in various ecosystems,such as wa-ter,glacier,sediment,and soil.As a key component of the global carbon cycle,DOM plays a cru-cial role in the regulating aquatic ecosystem dynamics and influencing global climate change.Com-posed of a highly heterogeneous mixture of organic compounds that contain diverse functional groups,DOM presents significant challenges for accurate characterization.This paper reviews the applica-tions of several analytical techniques in resolving the chemical composition of DOM,including excita-tion-emission matrices(EEM),nuclear magnetic resonance spectroscopy(NMR),high-resolution mass spectrometry(HRMS),gas chromatography-mass spectrometry(GC-MS),and atomic force microscopy(AFM).The advantages and limitations of each technique are critically assessed,there-by highlighting their respective contributions to a comprehensive understanding of DOM.These re-sults provide insights into the chemical composition and structure of DOM,spanning from macroscop-ic to microscopic perspectives.However,the understanding of the composition and structure of DOM still needs to be further enhanced.Future research should aim to improve analytical techniques,in-cluding the development of new sample pretreatment and derivatization methods to reduce matrix in-terference,and the application of machine learning and artificial intelligence algorithms to enhance the ability to extract information from complex data.关键词
溶解性有机质/天然有机质/化学组成/分子组成/化学结构Key words
dissolved organic matter/natural organic matter/chemical composition/molecular composition/chemical structure分类
化学化工引用本文复制引用
胡浩杰,何晨,史权..溶解性有机质化学组成表征方法与应用研究进展[J].分析测试学报,2025,44(8):1505-1515,11.基金项目
国家重点研发计划(2020YFA0607600) (2020YFA0607600)
中国石油大学(北京)科学基金(2462023YJRC003) (北京)