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天然气净化厂砜胺溶液体系发泡特性研究

刘可 李军强 黄娅 熊川 冉龙超 张伟

石油与天然气化工2025,Vol.54Issue(4):21-28,8.
石油与天然气化工2025,Vol.54Issue(4):21-28,8.DOI:10.3969/j.issn.1007-3426.2025.04.003

天然气净化厂砜胺溶液体系发泡特性研究

Research on foaming characteristics of sulfone amine solution system in natural gas purification plant

刘可 1李军强 1黄娅 1熊川 2冉龙超 3张伟3

作者信息

  • 1. 国家能源高含硫气藏开采研发中心||中国石油天然气集团公司高含硫气藏开采先导试验基地||中国石油西南油气田公司天然气研究院||国家市场监督管理总局重点实验室(天然气质量控制和能量计量)
  • 2. 中国石油西南油气田公司川中油气矿
  • 3. 中国石油西南油气田公司天然气净化总厂
  • 折叠

摘要

Abstract

Objective The aim is to study the foaming characteristics and the value of the foaming factor(K)of the sulfone amine desulfurization solution system.Method Firstly,in accordance with SY/T 6538-2016 Formulated selective desulfurization solvent,foaming experiments of sulfone amine solvents were conducted.The Key parameters such as foaming height and defoaming time were analyzed.The foaming characteristics of the sulfone amine solution system were semi-quantitatively described using relative foam density(Φ).The effects of liquid layer height,gas velocity,and temperature on foaming were investigated.Secondly,the K value was inferred by comparing the foaming condition of the sulfone amine solution system with the solution systems of known foaming factors.Result Firstly,increasing the liquid layer height significantly affected the foaming ratio of the sulfone amine lean solution.When the initial liquid layer height was increased from 30 mm to 100 mm,the foaming ratio decreased from 360%to 251%,but the half-life reached approximately 50%of the complete defoaming time.Secondly,the foaming height decreased with the increase of the gas velocity.The higher the gas velocity,the slower the defoaming rate and the better the foam stability.Thirdly,the defoaming rate increased with the rising of the temperature.Fourthly,the K value of fresh sulfone amine solution was close to that of MDEA aqueous solution,but the K value of the sulfone amine solution in the experimental device was speculated to be 0.55-0.64,and the foaming trend was obviously improved.Conclusion These experimental results can provide a reference for the design of natural gas purification plants based on sulfone amine solution system.

关键词

天然气净化/砜胺/脱硫/甲基二乙醇胺/发泡/发泡因子

Key words

natural gas purification/sulfone amine/desulfuzation/methyl diethanolamine/foaming/foaming factor

引用本文复制引用

刘可,李军强,黄娅,熊川,冉龙超,张伟..天然气净化厂砜胺溶液体系发泡特性研究[J].石油与天然气化工,2025,54(4):21-28,8.

基金项目

中国石油天然气集团有限公司科研项目"海相碳酸盐岩油气规模增储上产与勘探开发技术研究"(A202402) (A202402)

石油与天然气化工

OA北大核心

1007-3426

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